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超声波对金属相与陶瓷相间润湿角的影响

Influence of ultrasonic wave on wetting angle between metal phase and ceramic phase

  • 摘要: 金属相与陶瓷相间的润湿性对陶瓷刀具的性能起着重要作用,为了改善固−液界面结构,提高陶瓷材料的综合性能,研究了烧结过程中超声作用产生的能量对金属相与陶瓷相间润湿角的影响。根据粉末液相烧结理论,构建了固‒液双球冠润湿模型。依据润湿模型和最小能量原理,建立了润湿角与表面能、超声能、几何参数之间的关系。研究表明:在超声波作用下,固‒液、液‒气间的表面能增大,有利于液相烧结的进行,有助于减小润湿角;部分声能转化为热能,影响润湿角的变化;当超声波频率和振幅增大时,有利于润湿角的减小,提高金属相与陶瓷相间的润湿性。

     

    Abstract: The wettability between the metal phase and the ceramic phase plays an important role in the properties of the ceramic cutting tools. To improve the solid−liquid interface structure and enhance the comprehensive properties of the ceramic materials, the influence of the energy generated by ultrasonic during sintering on the wetting angle between the metal phase and the ceramic phase was studied. According to the theory of powder liquid phase sintering, the wetting model of the solid−liquid double spherical crown was established. Based on the wetting model and the minimal energy principle, the relationship among the wetting angle, surface energy, ultrasonic energy, and geometric parameters was established. The result shows that, the surface energy between the solid and liquid phases and between the liquid and gas phases increases by the ultrasonic wave, which is conducive to the progress of the liquid phase sintering and reduces the wetting angle; the part of acoustic energy is converted into the heat energy, which affects the wetting angle; when the ultrasonic frequency and amplitude increase, it is also beneficial to reduce the wetting angle and improve the wettability between the metal phase and the ceramic phase.

     

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