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许莹, 赵散玉, 夏朋昭, 何曜腾, 武泽倩, 蔡艳青(通讯作者). 造孔剂对医用多孔Ti/16Mg复合材料组织性能的影响[J]. 粉末冶金技术. DOI: 10.19591/j.cnki.cn11-1974/tf.2022110005
引用本文: 许莹, 赵散玉, 夏朋昭, 何曜腾, 武泽倩, 蔡艳青(通讯作者). 造孔剂对医用多孔Ti/16Mg复合材料组织性能的影响[J]. 粉末冶金技术. DOI: 10.19591/j.cnki.cn11-1974/tf.2022110005
Effects of pore-forming agent on microstructure and properties of biomedical porous Ti/16Mg composites[J]. Powder Metallurgy Technology. DOI: 10.19591/j.cnki.cn11-1974/tf.2022110005
Citation: Effects of pore-forming agent on microstructure and properties of biomedical porous Ti/16Mg composites[J]. Powder Metallurgy Technology. DOI: 10.19591/j.cnki.cn11-1974/tf.2022110005

造孔剂对医用多孔Ti/16Mg复合材料组织性能的影响

Effects of pore-forming agent on microstructure and properties of biomedical porous Ti/16Mg composites

  • 摘要: 采用粉末冶金工艺可制备出高强度的钛合金,但制备出的钛合金仍然存在着弹性模量偏高、孔隙特性不适合骨组织长入等问题。论文尝试采用粉末冶金工艺结合微波烧结法制备了弹性模量接近于人体骨骼、强度符合人体植入物要求的医用多孔Ti/16Mg复合材料。通过扫描电镜、X射线衍射、金相显微镜、压缩试验以及耐腐蚀性测试,探讨了造孔剂NH4HCO3粒径及添加量对复合材料的微观组织、力学性能和耐腐蚀性能的影响。结果表明:NH4HCO3对多孔Ti/16Mg复合材料的物相组成没有显著影响;试样孔隙随着NH4HCO3粒径的增大而增大,随着NH4HCO3添加量增加,试样孔隙率由16.64%增加到33.09%;当NH4HCO3粒径为165~198 μm、添加量为18wt.%时,试样的弹性模量为6.49 GPa、抗压强度为115 MPa,满足人体植入物的力学性能要求;不同粒径NH4HCO3对复合材料的耐腐蚀性影响不大;相同粒径条件下,随NH4HCO3添加量由0增加至24wt.%,复合材料的耐腐蚀性能略有下降,极化电阻由574.528 Ω?cm-2下降到139.236 Ω?cm-2。

     

    Abstract: High strength titanium alloys can be prepared by powder metallurgy process, but the titanium alloy still has some problems such as high elastic modulus and unsuitable pore properties for bone growth. In this paper, the biomedical porous Ti/16Mg composite material with elastic modulus close to that of human bone and strength meeting the requirements of human implants was prepared by powder metallurgy combined with microwave sintering method. The effects of particle size and addition amount of pore-making agent NH4HCO3 on microstructure, mechanical properties and corrosion resistance of the composites were investigated by scanning electron microscopy, X-ray diffraction, metallography, compression test and corrosion resistance test. The results show that NH4HCO3 has no significant effect on the phase composition of porous Ti/16Mg composites. The pore size of the sample increases with the increase of NH4HCO3 particle size, and the porosity of the sample increases from 16.64% to 33.09% with the increase of NH4HCO3 addition. When the particle size of NH4HCO3 is 165-198 μm and the addition amount is 18wt.%, the elastic modulus of the sample is 6.49 GPa and the compressive strength is 115 MPa, which can meet the mechanical property requirements of human implants. Different particle sizes of NH4HCO3 have little effect on the corrosion resistance of the composites. With the same particle size, the corrosion resistance of the composite decreases slightly and the polarization resistance decreases from 574.528Ω?cm-2 to 139.236Ω?cm-2 with the addition of NH4HCO3 increasing from 0 to 24wt.%.

     

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