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UO2/SiC全陶瓷微密封燃料制备及其高温导热性能

Preparation of fully ceramic microencapsulated pellets of UO2/SiC and research of its high temperature thermal conductivity

  • 摘要: 通过自研磨球化包覆和放电等离子烧结技术,调控升温速率、温度、压力、SiC添加量等参数,制备了一系列UO2/SiC复合全陶瓷微密封燃料芯块。利用金相显微镜、扫描电子显微镜观察了芯块的物相组成与结构特征。利用激光热导仪获得了芯块从室温到1200 ℃的热导率数据,讨论了不同工艺参数对芯块组织及热导率的影响。结果表明,UO2@SiC复合包覆颗粒具有良好的球形度和包覆效果,UO2/SiC复合芯块中SiC基体呈现三维连通的网状结构特征。烧结压力对芯块中UO2颗粒的结构完整性影响较大,烧结温度对碳化硅基体的形貌、致密度等影响较大。致密度低于95 %时,烧结温度对热导率的影响更大,致密度高于95 %时,SiC添加比例对热导率影响更大。所制备燃料芯块的热导率相比纯UO2提升最高达到256.6 %。

     

    Abstract: A series of UO2/SiC composite fully ceramic microencapsulated (FCM) pellets were prepared by self-grinding spheroidization coating and spark plasma sintering. The parameters such as heating rate, sintering temperature, sintering pressure, and SiC addition amount were regulated. The phase composition and structural characteristics of the pellets were observed by metallographic microscopy and scanning electron microscopy. The thermal conductivity (TC) of the pellets from room temperature to 1200 °C was obtained by a laser thermal conductivity meter. The effects of different process parameters on the microstructure and TC of the pellets were discussed. The results indicate that, the UO2@SiC composite particles are nearly spherical and well coated. The SiC matrix in UO2/SiC composite pellets exhibits a three-dimensional interconnected network structure. The sintering pressure has a significant influence on the structural integrity of UO2 particles in the pellets. The sintering temperature has a significant influence on the morphology and density of the SiC matrix. When the density is lower than 95 %, the sintering temperature has a greater effect on the TC of the fuel pellet, and when the density is higher than 95 %, the proportion of SiC added has a greater impact on the TC. The TC of the FCM pellets prepared in this study is increased by up to 256.6 % compared with pure UO2.

     

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