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二硼化钨(WB2)粉体制备、致密化烧结、微观结构和性能研究进展

Research Progress on the Powders Preparation, Densification sintering, Microstructure and Properties of Tungsten Diboride (WB2)

  • 摘要: 二硼化钨(WB2)因具有良好的力学性能、导电性、耐磨性和中子吸收能力等, 近年来受到研究者的广泛关注,被认为在机械加工工具和耐磨材料等领域有广阔应用前景。然而,与其他过渡金属硼化物类似,WB2存在烧结困难,导致实验制备的材料硬度远低于理论硬度的问题,严重限制了其应用。本文总结了WB2粉体的合成方法、烧结方法以及添加剂种类等对WB2陶瓷微观结构和力学性能的影响,对比不同方法之间的优缺点,以期探索更优的制备WB2粉体的合成方法和块体的制备工艺。

     

    Abstract: Tungsten diboride (WB2) has attracted great attention of researchers around the world due to its excellent mechanical properties, electrical conductivity, wear resistance, and neutron absorption ability. Therefore, it has been considered to have a wide application prospect as machining tools and wear-resistant materials. However, similar to other transition metal borides, the full consolidation of WB2 is difficult to achieve, and the reported experimental hardness values of WB2 are much lower than the theoretical hardness values, which severely limits its broad industrial applications. In the present work, the progress on synthesis methods of WB2 powders, sintering methods of WB2 bulk samples, and the effect of sintering aids on the microstructure and mechanical properties of WB2 ceramics were reviewed and summarized.

     

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