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溅射镀 Dy70Cu15Ga15晶界扩散对烧结钕铁硼磁体的磁性能影响

Effect of grain boundary diffusion of sputtered Dy70Cu15Ga15 on Magnetic Properties of Sintered Nd–Fe–B Magnets

  • 摘要: 通过磁控溅射技术在烧结Nd-Fe-B磁性材料的表面沉积合金薄膜, 研究晶界扩散Dy70Cu15Ga15合金烧结钕铁硼磁体的磁性能,及其在微观形态上的显微组织变化以及在电化学环境下的腐蚀行为表征。研究表明,晶界扩散处理可以显著提高磁体的矫顽力,磁体矫顽力从15.86kOe提高到19.46kOe,提升率达 22.7%,而剩磁和最大磁能积基本不降低。Dy元素扩散主要进入磁体晶界相中,优化了晶界相的分布,并存在于主相晶粒边界的缺陷区,取代主相中的Nd元素,形成(Nd,Dy)2Fe14B相,增强了缺陷层的各向异性场,抑制了反磁化畴形核。被取代的Nd元素进入晶界区增加了非磁性相的比例,对相邻主相进行有效磁隔绝,减弱了磁性耦合作用。低熔点CuGa合金共晶扩散打开了扩散通道,提高了Dy的扩散效率,优化了晶界结构。扩散后样品的主相衍射峰向大角度进行偏移,晶粒取向度更好;Dy70Cu15Ga15合金磁体在晶界处形成更稳定、腐蚀电位更高的富 Dy稀土相,优化了磁体的晶间组织结构,磁体的耐腐蚀性得到提高。

     

    Abstract: The magnetic properties of sintered neodymium iron boron magnets made of Dy70Cu15Ga15 alloy with grain boundary diffusion were studied using magnetron sputtering technology, as well as the microstructure changes and corrosion behavior characterization in the electrochemical environment. Research has shown that grain boundary diffusion treatment can significantly improve the coercivity of magnets. The coercivity of magnets has significantly increased from 15.86 kOe to 19.46 kOe, with an improvement rate of 22.7%, while residual magnetism and maximum magnetic energy product remain basically unchanged. The diffusion of Dy element mainly enters the grain boundary phase of the magnet, optimizes the distribution of grain boundary phase, and exists in the defect zone of the main phase grain boundary, replacing the Nd element in the main phase, forming (Nd, Dy) 2Fe14B phase, enhancing the anisotropic field of the defect layer, and suppressing the nucleation of demagnetized domains. The substitution of Nd elements into the grain boundary region increases the proportion of non-magnetic phases, effectively isolating adjacent main phases and weakening magnetic coupling. The eutectic diffusion of low melting point CuGa alloy opens up diffusion channels, improves the diffusion efficiency of Dy, and optimizes the grain boundary structure. After diffusion, the main phase diffraction peak of the sample shifts towards a larger angle, resulting in better grain orientation; The Dy70Cu15Ga15 alloy magnet forms a more stable and higher corrosion potential rich Dy rare earth phase at the grain boundaries, optimizing the intergranular structure of the magnet and improving its corrosion resistance.

     

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