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金属碳化物强化钨铼合金的制备及力学性能

Preparation and mechanical properties of refractory metal carbide reinforced tungsten‒rhenium alloys

  • 摘要: 采用传统无压烧结技术制备金属碳化物掺杂钨铼合金,对比研究了不同种类金属碳化物(ZrC、TiC、HfC)对钨铼合金微观组织和力学性能的影响,并分析讨论其强化机理。结果表明,金属碳化物可以增加钨铼合金的相对密度,减小晶粒尺寸,进而提高强度。碳化钛的强化效果最明显,最佳样品(W–4Re–0.8TiC)的相对密度、硬度和室温抗拉强度分别为96.77%、HV 396.1和233 MPa,对比钨铼合金基体分别提高了4.25%、21%和65%。同时,该合金在1200 ℃下具有585 MPa的抗压强度,对比钨铼合金基体提高了33%。

     

    Abstract: Metal carbide doped tungsten‒rhenium alloys were prepared by the traditional pressureless sintering method. The effects of ZrC, TiC, and HfC metal carbides on the microstructures and mechanical properties of tungsten‒rhenium alloys were studied, and the corresponding strengthening mechanisms were also analyzed. The results show that the metal carbides can increase the relative density of tungsten‒rhenium alloys, reduce the grain size, and enhance the corresponding strength. Among ZrC, TiC, and HfC metal carbides, the titanium carbide shows the most significant strengthening effect. The relative density, hardness, and tensile strength at room temperature of the best W–4Re–0.8TiC samples are 96.77%, HV 396.1, and 233 MPa, respectively, which are increased by 4.25%, 21% and 65% compared with the tungsten‒rhenium alloy matrix. Moreover, the as-optimized samples also have the compressive strength of 585 MPa at 1200 ℃, which is 33% higher than that of the tungsten‒rhenium alloy matrix.

     

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