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NbMoTaNiCr难熔高熵合金线弧增材制造成形性研究

Study on formability of NbMoTaNiCr refractory high entropy alloy by wire arc additive manufacturing

  • 摘要: 在前期制备难熔高熵合金缆式丝材基础上设计和研制NbMoTaNiCr难熔高熵合金缆式焊丝,采用非熔化极气体保护焊接(tungsten inert gas welding,TIG)旋转线弧增材制造技术开展NbMoTaNiCr难熔高熵合金成形实验。对NbMoTaNiCr难熔高熵合金进行五因素五水平成形正交实验,研究电流、电极间距、送丝速度、堆积速度等工艺参数对高熵合金成形质量的影响。结果表明,电流和送丝速度对NbMoTaNiCr难熔高熵合金成形质量的影响最大,焊道成形特性参数随电流、送丝速度和堆积速度的增大,大体上都呈现相同的先增大后减小趋势。根据正交实验结果分析得出,成形最优工艺参数组合为电流120 A,送丝速度8 mm·s−1,堆积速度120 mm·min−1,气体流量18 L·min−1,电极间距1 mm。同时发现所制备的NbMoTaNiCr难熔高熵合金主要由FCC相和少量μ相组成。本实验制备的NbMoTaNiCr难熔高熵合金成形层表面的平均硬度达到HV 911,超出目前所有文献报导的其他耐高温系高熵合金,达到非晶硬度水平。成形层的屈服强度为545.5 MPa,断裂应变为5.5%,断裂机制为解理断裂。

     

    Abstract: Based on the previous preparation of refractory high entropy alloy wire, NbMoTaNiCr refractory high entropy alloy wire was designed and developed, and the forming experiment of NbMoTaNiCr refractory high entropy alloy was carried out by using the tungsten inert gas welding (TIG) rotating arc additive manufacturing technology. The effects of current, electrode spacing, wire feed speed and accumulation speed on the forming quality of NbMoTaNiCr high entropy alloy were studied by orthogonal forming experiments with five factors and five levels. The results show that the forming quality of NbMoTaNiCr refractory high entropy alloy is most affected by current and wire feed speed. The forming characteristic parameters of weld bead increase first and then decrease with the increase of current, wire feed speed and accumulation speed. According to the orthogonal experiment results, the optimal process parameters are current 120 A, wire feed speed 8 mm·s−1, accumulation speed 120 mm·min−1, gas flow rate 18 L·min−1, electrode spacing 1 mm. The NbMoTaNiCr refractory high entropy alloy is mainly composed of FCC phase and a small amount of μ phase. The average hardness of the forming layer surface of NbMoTaNiCr refractory high entropy alloy prepared in this experiment reaches HV 911, which exceeds that of other high temperature resistant high entropy alloys reported in all literatures and reaches the level of amorphous hardness. The yield strength of the forming layer is 545.5 MPa, the fracture strain is 5.5%, and the fracture mechanism is cleavage fracture.

     

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