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超声振动对热变形钕铁硼富钕相分布的影响

The effect of ultrasonic vibration on the distribution of the Nd-rich phase in hot-deformed Nd-Fe-B

  • 摘要: 为探究超声振动对热变形钕铁硼富钕相分布的影响,采用MQU-F型快淬磁粉,通过热压和热变形工艺制备热变形钕铁硼磁体,并在磁体热变形过程中辅以超声振动。利用Abaqus软件对磁体常规和超声热变形过程中的变形应力进行分析,通过SEM、EDS图像对磁体中富钕相分布和成分进行分析,利用MPMS3磁性能检测系统对磁体中心和边界进行磁性能检测。结果表明,施加超声振动后,在声软化作用下,磁体变形应力降低,快淬带受挤压应力减小22.3%,快淬带内部富钕相挤出量减少,相邻快淬带和相邻晶粒之间的富钕相扩散通道变宽;受富钕相区域占比和相邻晶粒之间扩散通道的影响,富钕相在快淬带中的聚集区域发生改变。在声流作用下,热变形钕铁硼富钕相会受到声压等效力作用,使其集中分布的区域由磁体中间段向下端面扩散,在超声功率0-47 W?cm-2时,超声功率越大声压等效力越大,富钕相越容易在磁体下端面聚集。由于相邻快淬带之间的富钕相扩散通道变宽,富钕相沿磁体径向分布更加均匀,使热变形磁体中心和边界的矫顽力分别提高了25.4%和30.9%。

     

    Abstract: To investigate the influence of ultrasonic vibration on the distribution of the Nd-rich phase in hot-deformed Nd-Fe-B magnets, MQU-F type melt-spun powders were used to prepare hot-deformed Nd-Fe-B magnets through hot pressing and hot deformation processes, with ultrasonic vibration applied during the hot deformation stage. The deformation stress during the conventional and ultrasonic-assisted hot deformation processes of the magnets was analyzed using Abaqus software. The distribution and composition of the Nd-rich phase were examined through SEM and EDS imaging, while the magnetic properties at the center and edges of the magnets were detected using the MPMS3 magnetic property measurement system.The results indicate that after applying ultrasonic vibration, the deformation stress of the magnet is reduced due to the acoustic softening effect, leading to a 22.3% decrease in the compressive stress on the melt-spun ribbons and a significant reduction in the extrusion of the Nd-rich phase from within the ribbons. Consequently, the diffusion channels of the Nd-rich phase between adjacent melt-spun ribbons and neighboring grains are widened.Influenced by the proportion of the Nd-rich phase region and the diffusion channels between adjacent grains, the aggregation ?region of the Nd-rich phase within the melt-spun ribbons changes. Under acoustic streaming, the Nd-rich phase in hot-deformed Nd-Fe-B is subjected to an equivalent force from acoustic pressure, causing its concentrated distribution region to diffuse from the central section of the magnet toward the lower end face. When the ultrasonic power ranges from 0 to 47 W?cm-2, higher ultrasonic power results in greater equivalent force from acoustic pressure, making the Nd-rich phase more prone to accumulation at the lower end face of the magnet. Due to the widening of the diffusion channels of the Nd-rich phase between adjacent melt-spun ribbons, the Nd-rich phase is more uniformly distributed along the radial direction of the magnet, resulting in a significant enhancement of the coercivity, with increases of 25.4% and 30.9% observed at the center and edge of the hot-deformed magnet.

     

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