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超声振动对热变形钕铁硼中富钕相分布的影响

Effect of ultrasonic vibration on Nd-rich phase distribution in hot-deformed Nd–Fe–B magnets

  • 摘要: 为探究超声振动对热变形钕铁硼中富钕相分布的影响,采用MQU-F型快淬磁粉,通过热压和热变形工艺制备热变形钕铁硼磁体,并在磁体热变形过程中辅以超声振动。利用Abaqus软件对磁体常规热变形和超声热变形过程中的变形应力进行分析,通过扫描电镜、能谱仪分析磁体中富钕相分布,选用MPMS3磁性能检测系统对磁体中心区域和边界区域进行磁性能检测。结果表明,施加超声振动后,在声软化作用下,磁体变形应力降低,快淬带受挤压应力减小22.3%,快淬带内部富钕相挤出量减少,相邻快淬带和相邻晶粒之间的富钕相扩散通道变宽。受磁体不同区域富钕相面积分数差异和相邻晶粒之间扩散通道的影响,富钕相在快淬带中的聚集区域发生改变。在声流作用下,热变形钕铁硼富钕相会受到声压等效力作用,使其集中分布的区域由磁体中间段向下端面扩散。在超声功率0~47 W·cm−2时,超声功率越大,声压等效力越大,富钕相越容易在磁体下端面聚集。由于相邻快淬带之间的富钕相扩散通道变宽,富钕相沿磁体径向分布更加均匀,使热变形磁体中心和边界的矫顽力分别提高了25.4%和30.9%。

     

    Abstract: To investigate the influence of ultrasonic vibration on the Nd-rich phase distribution in hot-deformed Nd–Fe–B magnets, the MQU-F type melt-spun powders were used to prepare hot-deformed Nd–Fe–B magnets through hot pressing and hot deformation processes with ultrasonic vibration applied during the hot deformation stage. The deformation stress during the conventional and ultrasonic-assisted hot deformation processes of the magnets was analyzed by Abaqus software. The distribution and composition of the Nd-rich phases were examined by scanning electron microscope and energy disperse spectroscope, while the magnetic properties at the central region and the boundary region of the magnets were detected by the MPMS3 magnetic property measurement system. The results show that, after applying the ultrasonic vibration, the deformation stress of the magnets is reduced due to the acoustic softening effect, leading to a 22.3% decrease in the compressive stress on the melt-spun ribbons and a significant reduction in the extrusion of the Nd-rich phases from within the ribbons. Consequently, the diffusion channels of the Nd-rich phases between adjacent melt-spun ribbons and neighboring grains are widened. Influenced by the proportion of the Nd-rich phase region and the diffusion channels between adjacent grains, the aggregation region of the Nd-rich phases within the melt-spun ribbons changes. Under the acoustic streaming, the Nd-rich phases in hot-deformed Nd–Fe–B magnets are subjected to the equivalent force from acoustic pressure, causing the concentrated distribution region to diffuse from the central section of the magnets toward the lower end face. When the ultrasonic power ranges from 0 to 47 W·cm−2, the higher ultrasonic power results in the greater equivalent force from the acoustic pressure, making the Nd-rich phases more prone to accumulation at the lower end face of the magnets. Due to the widening of the diffusion channels of the Nd-rich phases between the adjacent melt-spun ribbons, the Nd-rich phases are more uniformly distributed along the radial direction of the magnets, resulting in the significant enhancement of coercivity, with increases of 25.4% and 30.9% observed at the center and edge of the hot-deformed magnets.

     

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