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机械力化学协同有机改性法氧化镁材料的制备及性能研究?

Preparation and properties of magnesium oxide materials by a mechanochemical synergistic organic modification method

  • 摘要: 为解决氧化镁粉体与有机基质结合中常常会出现排斥不相容、分散性不好、流动性差、容易团聚等缺陷,采用机械力化学协同有机改性的方法,通过混合和球磨对轻烧氧化镁进行处理。研究了改性剂种类、改性时间、改性剂用量对氧化镁的微观结构、亲油化度、活化指数、液体石蜡悬浮液粘度的影响。结果表明:当以硬脂酸钠为改性剂时,改性后氧化镁表面包覆着碎屑状物质;FTIR分析证实了直链烷基在表面的有效吸附。在最佳条件下(硬脂酸钠为改性剂,用量7%,改性时间5 h)下,产物的亲油化度为36.1%、活化指数为96.4%、石蜡悬浮液粘度为3270 mPa·s。此外,与未改性粉体相比,改性粉体表现出更好的有机相容性。

     

    Abstract: To address the defects such as exclusion incompatibility, poor dispersion, poor fluidity, and easy agglomeration in the combination of magnesium oxide powder and organic matrix, light-burned magnesium oxide was treated using a mechanochemical synergistic organic modification method through mixing and ball milling. The effects of modifier type, modification time, and modifier amount on the microstructure, lipophilic degree, activation index, and viscosity of liquid paraffin suspension of magnesium oxide were studied. The results show that when sodium stearate is used as the modifier, the surface of the modified magnesium oxide is coated with crumbly substances; FTIR analysis confirms the effective adsorption of straight-chain alkyl groups on the surface. Under optimal conditions (sodium stearate as the modifier, 7% dosage, 5 h of modification time), the product exhibits a lipophilic degree of 36.1%, activation index of 96.4%, and paraffin suspension viscosity of 3270 mPa·s. Furthermore, the modified powder demonstrates improved organic compatibility compared to unmodified powder

     

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