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2025年专刊-基于微观结构调控增强激光粉末床熔融CoCrNi中熵合金耐蚀性能

Enhancing Corrosion Resistance of Laser Powder Bed Fusion CoCrNi Medium-Entropy Alloy through Microstructure Regulation

  • 摘要: 增材制造CoCrNi中熵合金由于具有高强度、高塑韧性及快速制备复杂结构件等优势。然而,在平衡凝固过程中微观组织会发生局部位错富集,显著影响其海洋服役环境下的耐蚀性能及钝化膜特性。本文针对不同热处理后显微组织与腐蚀行为相关性展开研究,可以得出,随着热处理温度由900℃提高至1200℃,位错胞状结构逐渐消失,逐渐发生回复再结晶,由增材制造快速凝固的柱状晶转变为等轴晶,晶粒尺寸减小,析出相逐渐粗化;当900℃热处理后,腐蚀电位最高,维钝电流密度和腐蚀电流密度最小,耐蚀性能最好,随着热处理温度的提高,耐蚀性能逐渐下降。

     

    Abstract: Additively manufactured CoCrNi medium entropy alloys have some advantages such as high strength, high ductility, and rapid preparation of complex structural components. However, during the nonequilibrium solidification process, local dislocation enrichment occurs in the microstructure, significantly affecting its corrosion performance and passive film characteristics in marine service environments. The paper focuses on the correlation between microstructure and corrosion behavior after different heat treatments. It showed that as the heat treatment temperature increased from 900 ℃ to 1200 ℃, the dislocation cell structure gradually disappeared and underwent recovery and recrystallization, transforming from columnar crystals rapidly solidified in additive manufacturing to equiaxed crystals. The size of grain decreased and the precipitates gradually coarsened. After heat treatment at 900 ℃, the corrosion potential was the highest, the passivation current density and corrosion current were the smallest, and the corrosion resistance was the best. As the heat treatment temperature increased to 1200 ℃, the corrosion resistance gradually decreased.

     

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