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多元稀土氧化物添加对钨电极组织性能的影响研究

Study on the effect of multi-component rare earth oxide additions on the microstructure and properties of tungsten electrodes

  • 摘要: 本研究通过粉料冷等静压压制、中频烧结及旋转锻造的工艺,制备了纯钨(PW)、镧钨合金(W-La17)以及三元复合钨合金(W-X17)的棒材,探究了不同稀土氧化物配比对钨合金棒材的显微组织、第二相分布以及力学性能的影响,并分析讨论其强化机理和断韧机理。实验结果表明,稀土氧化物的添加能够有效细化钨基体晶粒尺寸,相比纯钨电极,稀土钨电极烧坯晶粒度等级提高一级,锻坯晶粒度等级提高一至二级,掺杂稀土氧化物有效防止钨棒烧结及锻造过程中的晶粒长大现象;通过锻造变形后,第二相元素可以均匀分散在钨基体中,并且稀土氧化物的添加对钨基体起到Orowan强化的作用,对钨电极的抗拉强度和硬度均有一定程度的提高,镧钨合金抗拉强度达到1149 MPa,三元钨合金抗拉强度达到1230 MPa,相比纯钨棒材,分别提高了70.98%和83.04%,硬度也由413 HV30提升至425 HV30和431 HV30,通过SEM分析纯钨和复合钨电极的室温拉伸断口形貌,均属于脆性断裂。

     

    Abstract: In this study, pure tungsten (PW), lanthanum tungsten alloy (W-La17) and ternary composite tungsten alloy (W-X17) rods were prepared through the processes of cold isostatic pressing, medium frequency sintering and rotary forging of powders, and the effects of different rare earth oxides ratios on the microstructures, the distribution of the second phase and the mechanical properties of the tungsten alloy rods were investigated, and the reinforcement and fracture toughness mechanisms were analyzed and discussed. The experimental results show that the addition of rare earth oxides can effectively refine the grain size of tungsten matrix, compared with the pure tungsten electrode, rare earth tungsten electrode sintering billet grain size grade increased by one grade, forging billet grain size grade increased by one to two grades, and the doping of rare earth oxides effectively prevents the grain growth phenomenon of tungsten rods in the process of sintering and forging; after the deformation of the second phase through the forging, the second phase elements can be dispersed uniformly in the tungsten matrix and the addition of rare earth oxides plays an omega role in the tungsten matrix. After forging and deformation, the second phase elements can be evenly dispersed in the tungsten matrix, and the addition of rare earth oxides plays the role of Orowan reinforcement of the tungsten matrix, which improves the tensile strength and hardness of the tungsten electrode to a certain extent, the tensile strength of lanthanum tungsten alloy reaches 1,149 MPa, and the tensile strength of ternary tungsten alloy reaches 1,230 MPa, which is 70.98% and 83.04% higher than that of pure tungsten rods, and the hardness is also raised from 413 HV30 to 425 HV30 and 431 HV30, and the fracture morphology of pure tungsten and composite tungsten electrode was analyzed by SEM, which were both brittle fracture.

     

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