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多元稀土氧化物对钨电极组织性能的影响

Effect of multi-component rare earth oxide on microstructure and properties of tungsten electrodes

  • 摘要: 通过冷等静压、中频烧结及旋转锻造的工艺制备了纯钨(PW)、镧钨合金(W-La17)以及三元复合钨合金(W-X17)棒材,研究了稀土氧化物对钨合金棒材显微组织、第二相分布以及力学性能的影响,并讨论了强化机理和断韧机理。结果表明,稀土氧化物的添加能够有效细化钨基体晶粒尺寸,相比纯钨电极,稀土钨电极烧结坯晶粒度等级提高1级,锻造坯晶粒度等级提高1~2级,掺杂稀土氧化物可有效防止钨棒烧结及锻造过程中的晶粒长大现象。经锻造变形后,第二相元素可以均匀分散在钨基体中,稀土氧化物的添加对钨基体起到Orowan强化作用,对钨电极的抗拉强度和硬度均有一定程度的提高;镧钨合金抗拉强度达到1149 MPa,三元钨合金抗拉强度达到1230 MPa,相比纯钨棒材,分别提高了70.98%和83.04%,硬度也由HV30 413(纯钨)提升至HV30 425(镧钨合金)和HV30 431(三元钨合金)。纯钨和复合钨电极的室温拉伸断口均属于脆性断裂。

     

    Abstract: Pure tungsten (PW), lanthanum-tungsten alloy (W-La17), and ternary composite tungsten alloy (W-X17) rods were prepared by cold isostatic pressing, intermediate frequency sintering, and swaging. The effect of rare earth oxide on the microstructure, second-phase distribution, and mechanical properties of the tungsten alloy rods was investigated, and the strengthening mechanism and fracture-toughness mechanism were analyzed and discussed. The results show that the addition of rare earth oxide effectively refines the grain size of tungsten matrix. Compared with pure tungsten electrodes, the sintered billets of the rare earth-doped tungsten electrodes exhibit one grade higher in granule size, while the swaged billets show one to two grades higher, indicating that doping by rare earth oxide effectively prevents the grain growth during sintering and swaging. After swaging deformation, the second-phase elements are uniformly dispersed in the tungsten matrix. Moreover, the addition of rare earth oxide contributes to Orowan strengthening in the tungsten matrix, leading to a certain degree of improvement in tensile strength and hardness of the tungsten electrodes. The lanthanum-tungsten alloys achieve the tensile strength of 1149 MPa, while the ternary tungsten alloys reach 1230 MPa, representing increases of 70.98% and 83.04%, respectively, compared to the pure tungsten rods. The hardness also increases from HV30 413 (pure tungsten) to HV30 425 (lanthanum-tungsten alloys) and HV30 431 (ternary tungsten alloys). The room-temperature tensile fracture of both pure tungsten and composite tungsten electrodes reveals the brittle fracture characteristics.

     

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