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WC颗粒增强Ni基复合涂层的微观组织与力学性能

Microstructure and mechanical properties of WC particle reinforced Ni-based composite coatings

  • 摘要: 针对WC颗粒在复合涂层制备过程中易出现的分层与分解问题,采用WC颗粒与Ni基合金复合粉体作为熔覆材料,利用激光熔覆技术在34MnB5钢表面制备WC颗粒增强Ni基复合涂层,系统探究熔覆功率对涂层微观组织与性能的影响规律。通过光学显微镜、扫描电镜、能谱分析仪、X射线衍射仪等手段表征粉体及涂层微观组织与物相组成,利用Image J软件测试涂层厚度和WC体积分数,采用显微硬度计和ASTM G65标准磨损试验测试涂层硬度与摩擦学性能。结果表明:随着熔覆功率升高,涂层表面质量显著改善,厚度增加,但WC颗粒体积分数从41.6%降至30.2%;高功率导致WC颗粒分解加剧,游离的W、C溶入Ni基合金基体或原位生成富W碳化物,基体硬度得以提高;摩擦磨损试验证实,在低应力磨损条件下,涂层的耐磨性能与WC颗粒体积分数呈正相关,优选1.4 kW激光熔覆功率;1.8 kW熔覆的涂层裂纹数量更少,表面质量更高,因此在表面质量与抗冲击性需求的工况更具综合优势。

     

    Abstract: To resolve the problem of WC particle delamination and decomposition during the preparation of the composite coatings, the WC particles and Ni-based alloy composite powders were employed to fabricate the WC particle reinforced Ni-based composite coatings by laser cladding technology on 34MnB5 steels. The effect of cladding power on the microstructure and properties of the coatings was systematically investigated. The microstructure and phase composition of the powders and coatings were characterized by optical microscope, scanning electron microscope, energy dispersive spectrometer, and X-ray diffractometer. The layer thickness and WC volume fraction were measured by Image J software, while the hardness and tribological properties were evaluated by microhardness testing and ASTM G65 standard wear experiments. The results show that the hardness and surface morphology of the composite coatings are significantly improved with increasing cladding power, however, the WC volume fraction in coatings is decreased from 41.6% to 30.2%. When the cladding power is high, the overheating may lead to the decomposition of WC particles to form free C and W atoms, which can be dissolved into the Ni-based matrix or formed W-rich carbides lead to the hardness elevating of the matrix. The tribological properties testing show that the wear resistance is positively correlated with the volume fraction of WC particles under low-stress abrasion condition. So, the wear resistance of the composite coatings is preferred when the cladding power is 1.4 kW. However, when the cladding power is 1.8 kW, there is almost no cracks and higher surface quality, which is suitable for applications on the balancing condition of surface qualities and impact resistance.

     

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