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Ti(C,N)基金属陶瓷的研究现状及发展趋势综述

Review on Research Status and Development Trends of Ti(C,N)-Based Cermets

  • 摘要: Ti(C,N)基金属陶瓷凭借卓越的综合性能,已成为传统结构件及高温结构件的重要候选材料。近年来,研究焦点逐步由成分设计与制备工艺转向微观结构调控与梯度材料,通过引入高熵合金(HEA)、金属间化合物等新型粘结相,结合放电等离子体烧结、微波烧结及增材制造等先进技术,研究者在实现“芯-环”结构调控、强韧性协同提升与梯度结构的构建等领域,开展了大量探索并取得了显著进展。本文系统梳理了Ti(C,N)基金属陶瓷在粘结相优化、梯度结构调控与绿色烧结等方面的研究进展,重点探讨了低钴化/无钴化体系、多尺度梯度结构的构建方法,以及气氛烧结、放电等离子体烧结和3D打印等工艺对组织与性能的调控机制。基于Ti(C,N)基金属陶瓷传统与新兴制备技术的对比,可为研究者的工艺选择与优化提供理论与实践依据。

     

    Abstract: Owing to their outstanding comprehensive properties, Ti(C,N)-based cermets have emerged as significant candidate materials for both traditional structural components and high-temperature structural applications. In recent years, research focus has gradually shifted from composition design and preparation techniques towards microstructure regulation and gradient materials. By introducing novel binder phases such as high-entropy alloys (HEAs) and intermetallic compounds, combined with advanced technologies like spark plasma sintering (SPS), microwave sintering, and additive manufacturing (AM), researchers have conducted extensive exploration and achieved remarkable progress in areas including the regulation of 'core-rim' structures, the synergistic enhancement of strength and toughness, and the construction of gradient structures. This article systematically reviews the research progress in Ti(C,N)-based cermets concerning binder phase optimization, gradient structure regulation, and green sintering processes. It places particular emphasis on low-cobalt or cobalt-free systems, methodologies for constructing multi-scale gradient structures, and the underlying mechanisms by which processes such as atmosphere sintering, spark plasma sintering (SPS), and 3D printing regulate microstructure and properties. Based on a comparison between traditional and emerging preparation technologies for Ti(C,N)-based cermets, this review aims to provide both theoretical and practical guidance for researchers in process selection and optimization.

     

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