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烧结温度对Ti600合金泡沫孔隙及力学性能的影响

Effect of Sintering Temperature on Pore Structure and Mechanical Properties of Ti600 Alloy Foam

  • 摘要: 本研究以Ti600高温钛合金粉末(Ti-6Al-2.8Sn-4Zr-0.5Mo-0.4Si-0.1Y)为基体,尿素为占位体,采用粉末冶金法制备泡沫钛材料,利用光学金相显微镜、扫描电镜以及万能力学试验机系统探究烧结温度(1100 ℃–1400 ℃)对泡沫钛宏微观结构特征及力学性能的影响。结果表明:随着烧结温度升高,孔壁逐渐致密化,孔隙率从1100℃的67.61%显著降低至1400℃的61.31%,平均孔径持续缩小(1400 ℃时为1.194 mm);压缩强度随温度提升持续增加,在1300 ℃达峰值82.08 MPa,1400 ℃时降至78.20 MPa;杨氏模量在1300 ℃达最优值1.735 GPa,1400 ℃时因晶粒粗化降至1.719 GPa;能量吸收效率于1300 ℃达到最高值28.131 MJ/m3。综合结构特征与性能指标,在本实验条件下1300 ℃为最佳烧结温度,此时孔壁充分致密且孔隙分布均匀,同时兼具最高压缩强度与最优能量吸收能力。

     

    Abstract: Porous titanium foams were fabricated from Ti600 high-temperature alloy powder (Ti-6Al-2.8Sn-4Zr-0.5Mo-0.4Si-0.1Y) via the powder metallurgy route, utilizing urea as a space holder. The effects of sintering temperature (1100–1400 °C) on the microstructure, porosity, and mechanical properties were systematically investigated using optical microscopy, scanning electron microscopy (SEM), and uniaxial compression tests. With increasing sintering temperature, the pore walls became progressively denser, resulting in a significant decrease in porosity from 67.61% at 1100 °C to 61.31% at 1400 °C. The average pore size also consistently decreased, reaching 1.194 mm at 1400 °C. The compressive strength increased steadily with temperature, peaking at 82.08 MPa at 1300 °C before slightly declining to 78.20 MPa at 1400 °C due to over-sintering. Similarly, the Young's modulus reached an optimum value of 1.735 GPa at 1300 °C, then marginally decreased to 1.719 GPa at 1400 °C, attributed to grain coarsening. The energy absorption efficiency also peaked at 1300 °C with a value of 28.131 MJ/m3. Consequently, under the present experimental conditions, 1300 °C was identified as the optimal sintering temperature, yielding well-densified pore walls and a uniform pore distribution, resulting in superior compressive strength and energy absorption capacity.

     

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