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改性粘结剂在金属注射成形中的界面与性能调控研究进展

Research progress on interface mechanisms and performance regulation of modified binders in metal injection molding

  • 摘要: 粘结剂是金属注射成形的核心组分,粘结剂改性是提升喂料、生坯与烧结件综合性能的重要手段。本文综述金属注射成形改性粘结剂的研究进展,归纳物理改性、化学改性、粉末表面处理协同改性三类粘结剂改性方法,从界面相互作用、流变性能调控、脱脂-烧结稳定性三个角度剖析粘结剂改性内在机理。分析表明,氢键与共价键是强化粉末-粘结剂界面结合的主要化学作用;针对塑基、蜡基、混合粘结剂体系,需要差异化调控分子链缠结和复配粘度梯度聚合物,优化假塑性流动行为;粘结剂组分设计可调控脱脂阶段孔隙演化,减少残碳缺陷,实现脱脂-烧结过程协同匹配。改性粘结剂能够提高生坯密度与密度均匀性,改善生坯保形能力,降低烧结件残碳,将烧结相对密度提升至理论密度95%~99%以上。粘结剂改性可为高精度粉末冶金零部件规模化制备提供技术支撑,推动金属注射成形向绿色化方向发展。

     

    Abstract: Binders are the core component of metal injection molding (MIM), and the binder modification is an important approach to improve the comprehensive properties of feedstocks, green parts, and sintered components. The research progress of modified binders for metal injection molding was reviewed in this paper, and the modification strategies were summarized, including physical modification, chemical modification, and powder surface-treatment synergistic modification. The internal modification mechanisms were analyzed from interfacial interaction, rheological property regulation, and debinding-sintering stability. In the results, the hydrogen bonds and covalent bonds serve as the major chemical forces to strengthen powder-binder interfacial bonding. For the plastic-based, wax-based, and mixed binder systems, adjusting molecular chain entanglement and compounding polymers with viscosity gradients should be adopted to optimize the pseudoplastic flow behavior. The rational component design of binders can regulate the pore evolution during debinding, reduce the residual-carbon defects, and realize the coordinated matching between debinding and sintering processes. Modified binders can increase the green density and distribution uniformity, improve the shape retention of green bodies, mitigate the carbon residue in sintered parts, and raise the relative sintered density to more than 95%~99% of theoretical density. It is concluded that the binder modification provides the technical support for large-scale fabrication of high-precision powder-metallurgy components and promotes the green development of metal injection molding technology.

     

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