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WO3碳热还原过程的非等温动力学研究

Non-isothermal Kinetics of the Carbothermal Reduction of WO3

  • 摘要: 碳热还原WO3是制备钨粉的主要方式之一,而WO3的还原动力学直接影响着钨粉的形貌、粒径和均匀性。本文基于热分析方法,系统研究了WO3在碳热还原过程中的非等温动力学行为。研究结果表明:WO3非等温碳热还原过程中,表观活化能随着转化率的增大由586.5 kJ·mol-1逐渐降低至307.9 kJ·mol-1,平均活化能为419.0 kJ·mol-1;还原过程遵循二级反应模型,机理函数G(α)=(1-α)-1-1,线性相关系数R2>0.99。通过无模型法和模型拟合法获得的表观活化能、机理函数和指前因子等动力学参数,构建了可预测WO3碳热还原过程的动力学模型,为碳热还原技术的优化提供了理论依据。

     

    Abstract: Carbothermal reduction of WO3 is one of the primary methods for producing tungsten powder, and the reduction kinetics of WO3 directly influence the morphology, particle size, and uniformity of the final powder. In this study, the non-isothermal kinetic behavior of WO3 during carbothermal reduction was systematically investigated using thermal analysis techniques. The results show that the apparent activation energy decreases from 586.5 kJ·mol-1 to 307.9 kJ·mol-1 as the conversion increases, with an average value of 419.0 kJ·mol-1. The reduction process follows a second-order reaction model with a kinetic function of G(α) = (1-α)-1-1, and the linear correlation coefficient R2 exceeds 0.99. Based on the apparent activation energies, kinetic functions, and pre-exponential factors obtained from both model-free and model-fitting methods, a kinetic model capable of predicting the carbothermal reduction behavior of WO3 was established, providing a theoretical foundation for optimizing carbothermal reduction processes.

     

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