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BN增强Ni60-Cr3C2超高速激光熔覆涂层微观组织及性能研究

Microstructure and Performance of BN-Reinforced Ni60-Cr3C2 Coatings Fabricated by Ultra-High-Speed Laser Cladding

  • 摘要: 为解决机械零部件表面耐磨耐蚀性能不足的问题,本研究实现了BN增强Ni60-Cr3C2涂层的超高速激光熔覆制备。通过 X 射线衍射(XRD)、光学显微镜 (OM)、扫描电子显微镜(SEM)、维氏显微硬度测试、摩擦磨损实验及电化学测试,系统分析了BN对Ni60-Cr3C2涂层微观组织与性能的影响。结果表明,Ni60-Cr3C2涂层主要由Cr3Ni2、Cr1.12Ni2.88、Cr7C3、Fe3C组成。在添加BN后,涂层中原位生成了Fe2B、Cr2N、Cr2B3,BN能促进涂层中残留Cr7C3分解以及富Cr枝晶网络形成。Ni60-Cr3C2-5%BN涂层组织均匀性与耐磨性能显著提升,其体积磨损量较Ni60-Cr3C2涂层降低53.3%。此外,Ni60-Cr3C2-5%BN涂层腐蚀电流密度为1.28×10-6 A·cm-2,较Ni60-Cr3C2降低81.0%,其电荷转移电阻达5562 Ω?cm2,为Ni60-Cr3C2涂层的2.2倍,表现出更优的耐腐蚀性能。

     

    Abstract: To address the problem of insufficient wear and corrosion resistance on the surfaces of mechanical components. In this study, BN-modified Ni60-Cr3C2 coatings were fabricated using an ultra-high-speed laser cladding technique. The effects of BN on the microstructure and properties of the coatings were systematically investigated by X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), Vickers microhardness testing, friction-wear experiments, and electrochemical measurements. ?The results show that the Ni60-Cr3C2 coating is mainly composed of Cr3Ni2, Cr1.12Ni2.88, Cr7C3 and Fe3C. After the addition of BN, in-situ Fe2B, Cr2N, and Cr2B3 phases were generated, and BN further promoted the decomposition of Cr3C2 as well as the formation of Cr-rich dendritic networks. The structural uniformity and wear resistance were significantly improved, with its wear volume reduced by 53.3% compared with the Ni60-Cr3C2 coating. Moreover, BN markedly enhanced the corrosion resistance of the coating. The corrosion current density of the Ni60-Cr3C2-5%BN coating was 1.28×10-6 A·cm-2, 81.0% lower than that of the Ni60-Cr3C2 coating, and its charge-transfer resistance reached 5562 Ω·cm2, which is 2.2 times that of the unmodified coating.

     

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