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固溶处理对FGH96合金管坯晶粒长大行为的影响研究

Study on the Effect of Solution Treatment on Grain Growth Behavior of FGH96 Alloy Tube Billets

  • 摘要: 本文采用光学显微镜(Optical Microscopy, OM)、扫描电子显微镜(Scanning Electron Microscopy, SEM)及电子背散射衍射(electron backscatter diffraction, EBSD)等表征手段,系统研究了FGH96合金在1130 ℃~1155 ℃温度区间的晶粒长大行为。研究结果显示,管坯晶粒尺寸随固溶温度升高及保温时间延长呈逐步增大趋势;固溶处理过程中,γ′相、原始颗粒边界原始颗粒边界(prior particle boundaries,PPB)区域分布的大量弥散MC碳化物颗粒,以及退火孪晶,均对晶界起到有效钉扎作用,进而抑制晶粒长大,使合金晶粒尺寸始终控制在18 μm以下。基于Arrhenius型晶粒长大动力学模型进行拟合计算,当时间指数n=2时,拟合决定系数R2达到最大值(R2=0.89565),拟合效果最优,且实验值与模型预测值的误差最小,仅为30.15 %。热处理时γ′相的大量溶解及PPB上MC碳化物及氧化物分布不均导致晶界局部钉扎力薄弱,为部分晶粒优先长大创造了条件,最终导致合金出现异常粗大晶粒与混晶组织。

     

    Abstract: This paper systematically investigates the grain growth behavior of FGH96 alloy in the temperature range of 1130 °C to 1155 °C using characterization methods such as OM, SEM and EBSD. The results indicate that the grain size of the tube billet gradually increases with the rise in solution treatment temperature and the extension of holding time. During the solution treatment process, the γ′ phase formed, a large number of dispersed MC carbide particles distributed in the PPB region, and annealing twins all effectively pin the grain boundaries, thereby inhibiting grain growth and keeping the alloy grain size consistently below 18 μm. Based on the Arrhenius-type grain growth kinetics model, when the time exponent n=2, the coefficient of determination R2 reaches its maximum value (R2=0.89565), indicating the optimal fitting effect, and the error between the experimental values and the model predictions is minimized to only 30.15 %. During heat treatment, the extensive dissolution of γ′ phases and the uneven distribution of MC carbides and oxides along PPB weaken the local grain boundary pinning force. This provides favorable conditions for the preferential growth of partial grains, ultimately resulting in abnormally coarse grains and a mixed grain structure in the alloy.

     

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