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中高变形量热轧纯钨棒退火的组织与性能演化研究

Research on the Evolution of Microstructure and Properties of Medium and High Deformation Hot-rolled Pure Tungsten Rods after annealing

  • 摘要: 以高纯钨粉为原料,通过冷等静压成型、真空感应烧结及中温多道次热轧工艺,制备得到总变形量60%的热轧纯钨棒,随后在1350 ℃条件下进行1~32 h梯度等温退火试验。采用金相观察、电子背散射衍射表征以及硬度与密度等测试,并结合Johnson-Mehl-Avrami-Kolmogorov模型,研究中高变形量热轧纯钨棒退火的组织与性能演化。结果表明:高变形量热轧纯钨1350 ℃下退火保温8 h以回复过程为主,位错重排形成亚晶界,γ纤维织构强度下降。延长保温至16 h,发生完全再结晶,变形晶粒消失,织构趋于随机并出现微弱θ纤维织构,晶粒粗化至40~60 μm且尺寸分布明显重构。同时,动力学分析显示,退火再结晶行为遵循JMAK模型,但其Avrami指数低于理想再结晶模型的理论阈值,再结晶过程主要通过亚晶合并与晶粒粗化实现。此外,退火过程导致硬度由轧制态的477.63 HV10逐步降低并稳定于392.16 HV10附近;相对密度则因空位扩散、孔洞演变与移动晶界之间的竞争作用而呈现动态波动特征。

     

    Abstract: Hot?rolled pure tungsten rods with a total deformation of 60% were fabricated from high?purity tungsten powder via cold isostatic pressing, vacuum induction sintering and multi?pass hot rolling at moderate temperature. A series of isothermal annealing treatments were subsequently performed at 1350 oC for holding durations ranging from 1 h to 32 h. The microstructural evolution and property development of the hot-rolled pure tungsten rods during annealing were systematically investigated by means of metallographic observation, electron backscatter diffraction (EBSD), and hardness and density measurements, combined with Johnson-Mehl-Avrami-Kolmogorov (JMAK) kinetic analysis. The results demonstrate that within the first 8 h of annealing at 1350 °C, the microstructure is dominated by recovery, during which dislocation rearrangement gives rise to subgrain boundaries and the γ-fiber texture intensity decreases. Full recrystallization is triggered when the holding time is extended to 16 h, whereby the deformed grains are eliminated, the texture evolves toward a random orientation accompanied by a weak θ-fiber component, and the grains coarsen to 40-60 μm with a markedly reshaped grain-size distribution. Kinetic analysis reveals that the recrystallization behavior is well described by the JMAK model; however, the obtained Avrami exponent is lower than the theoretical value for ideal recrystallization, indicating that recrystallization is primarily governed by subgrain coalescence and grain coarsening. Moreover, the Vickers hardness decreases gradually from 477.63 HV10 in the as-rolled state and eventually stabilizes at approximately 392.16 HV10, while the relative density fluctuates during annealing, which is attributed to the competitive interplay among vacancy diffusion, pore evolution, and migrating grain boundaries.

     

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