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热等静压用陶瓷模的烧结

Sintering of Ceramic Mold in HIP Process

  • 摘要: 热等静压用陶瓷模既要具有一定的室温强度,又要具有良好的高温塑性变形能力,因而需要采取特殊的烧结工艺。本工作分析了加热过程中陶瓷模中的物理、化学变化,设计了缓慢加热/冷却、分段保温的烧结方法。研究结果表明,陶瓷模材料中的SiO2颗粒在烧结过程中发生了多次晶型转变,并伴随有强烈的体积变化。采用设计的烧结方法,较好地控制了因晶型转变而引起的体积变化,避免了陶瓷模开裂或畸变。此外还发现,加入MgO和TiO2助烧剂,显著降低了烧结温度,使陶瓷模可在1100℃左右烧结。

     

    Abstract: Ceramic mold used in HIP process was required to has not only proper strength at room temprature but also better plasticity at elevated temperature so the ceramic mold must be sintered in a special way.Physical and chemical changes of sintering the ceramic mold were investigated,and a novel sintering process was designed.Experimental results showed that the transformations of crystal type in SiO2 particles lead to violent changs of the particle volume,which can result incracking or distorting of the ceramic mold.However,the volume change of SiO2 particles was properly controlled with the designed sintering process and any cracking or distorting of the ceramic mold was avoided.It was found that addition of MgO and TiO2 particle decreased the sintering temperature remarkablly and the ceramic mold could be sintered just at 1100℃.

     

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