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钯活化钼的烧结

ACTIVATED SINTERING OF MOLYBDENUM BY ADDING PALLADIUM

  • 摘要: 本文研究了钯的加入量、烧结温度和烧结时间对钼的密度的影响。实验结果表明,钯的最适宜的加入量为0.5wt%左右。在这个最佳量下钼的最适宜的烧结温度为1150℃。利用实验数据计算了钯活化钼烧结的控制收缩机理的特性指数n和表观活化能Q。得习n为3.1—3.4和Q为61—62.5kcal/mol。从而得出钯活化钼的烧结机理以晶界扩散为主。本文对钯在钼粉粒子表面上的分布状态,提出了看法。

     

    Abstract: The present paper studies the influence of quantity of palladium added in molybdenum, sintering temperature and sintering time on densities of molybdenum The experiments show that optimum quantity of palladium is around 0.5wt.%.The optimum sintering temperature of molybdenum with about 0.5wt.% pd is at 1150℃.The characteristic exponent(n) for indicating dominant densifieation mechanism and apperent activation energy(Q) were calculated by using experimenltal data.The n and Q obtained is 3.1-3.4 and 61-62.5 kcal mol-1 respectively. It is concluded that the activated sintering mechanism of molybdenum by palladium is mainly derived from boundary diffusion. Some cosiderations of the distribution state of palladium on the surface of molybdenum particles are also given in this paper.

     

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