稀土添加剂对WC-20(Fe/Co/Ni)硬质合金性能的影响
INFLUENCE OF RARE-EARTH ADDITIONS ON THE CONVENTIONAL PROPERTIES OF WC-20(Fe/Co/Ni) CEMENTED CARBIDES
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摘要: 在铁镍部分代钴的基础上,采用常规硬质合金生产工艺,用不同含量的混合稀土作为添加剂进行了实验。结果表明,添加稀土可使合金硬度有较为明显的提高;对抗弯强度也有一定的影响,当稀土添加量为0.2%时,合金抗弯强度提高达5.8%左右;此外,加入稀土后,合金的耐磨性亦有所增强。断口扫描及能谱分析发现,WC/粘结相界面有球状稀土析出物存在,并富集较多杂质;X衍射分析显示稀土的添加可改变粘结相中γ-Fe/Co/Ni和α-Fe/Co/Ni的相对数量。文章依据实验结果对稀土影响WC-Fe/Co/Ni合金的原因进行了初步探讨。Abstract: On the basis of replacing cobalt Partly with iron and nickel, and the influence of rare-earth content on properties of WC-20(Fe/Co/Ni) alloy prepared conventional convess process was investigated. The results results show that when proper content of rare-earth is added, the alloy's hardness increases obviously (HRA0.2~1.5). When rare earth about 0.2 percent Weight of binder phase is added, the alloy's transverse rupture strength increases 5.8%, and the wear-resistance improves. The spherical pecipitates (containing RE) are found at the interface of WC/binder phase by SEM. X-ray analysis shows that the addition of rare-earth can change the relative content of the γ-Fe/Go/Ni and α-Fe/Co/Ni. The influence mechanism of rare-earth on the alloy's properties was discussed according to the results mentioned above.