AdvancedSearch
ZHONG Xiang, HA Min, DONG Ning-li, ZHENG Wei, SHI Wen-feng. Study on spherical silver powders prepared by silver carbonate precursor modified by cladding-thermal decomposition[J]. Powder Metallurgy Technology, 2018, 36(6): 438-444. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.06.007
Citation: ZHONG Xiang, HA Min, DONG Ning-li, ZHENG Wei, SHI Wen-feng. Study on spherical silver powders prepared by silver carbonate precursor modified by cladding-thermal decomposition[J]. Powder Metallurgy Technology, 2018, 36(6): 438-444. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.06.007

Study on spherical silver powders prepared by silver carbonate precursor modified by cladding-thermal decomposition

More Information
  • Corresponding author:

    ZHONG Xiang, E-mail: xicaiyuanx@163.com

  • Received Date: May 10, 2018
  • Available Online: September 03, 2021
  • The silver carbonate precursor was prepared by chemical precipitation method using ammonium carbonate as precipitation agent and silver nitrate solution as raw material. The cladding silver carbonate precursor was modified by parallel flow precipitation, and the single dispersed spherical silver powders were obtained by the thermal decomposition of modified precursor. The crystallinity, purity, dispersibility, fallibility, and morphology of silver powders were characterized by X-ray diffraction (XRD), particle size distribution (PSD) statistics, tap density test, and scanning electron microscopy (SEM), the influences of silver nitrate solution concentration and methanol adding on the dispersibility and particle size distribution of silver carbonate precursor were discussed, and the effects of cladding ratio (by mole) of magnesium carbonate and silver carbonate on the dispersibility of silver powders were studied. In the results, the single dispersed spherical silver powders can be obtained by cladding-thermal decomposition, which has the advantages of simple equipment, less input, good dispersibility, and the concentrated particle size distribution of products; when the silver nitrate solution concentration is 0.2~0.5 mol/L, the particle size of spherical silver powders is 0.5~2.5 μm; the dispersibility of silver carbonate precursor can be adjusted by adding methanol, the methanol dosage (the volume fraction of methanol in silver nitrate solution) should be controlled as 5%~10%; when the silver nitrate solution concentration is 0.5 mol/L, the methanol dosage by volume is 5%, the optimum dispersibility of silver powders is obtained as the cladding ratio (by mole) of magnesium carbonate and silver carbonate is 2:1.
  • [1]
    谢炜, 郑亚亚, 匡加才, 等. 以聚乙烯吡咯烷酮为分散剂制备球形银粉的研究. 粉末冶金工业, 2015, 25(1): 23 https://www.cnki.com.cn/Article/CJFDTOTAL-FMYG201501007.htm

    Xie W, Zheng Y Y, Kuang J C, et al. Study on preparation of spherical silver powders with polyvinylpyrrolidone as dispersant. Powder Metall Ind, 2015, 25(1): 23 https://www.cnki.com.cn/Article/CJFDTOTAL-FMYG201501007.htm
    [2]
    刘书祯, 谈定生, 吕超君. 抗坏血酸还原制备微细银粉的研究. 粉末冶金工业, 2009, 19(2): 5 https://www.cnki.com.cn/Article/CJFDTOTAL-FMYG200902003.htm

    Liu S Z, Tan D S, Lv C J. Research on preparation fine silver powder by ascorbic acid reduction. Powder Metall Ind, 2009, 19(2): 5 https://www.cnki.com.cn/Article/CJFDTOTAL-FMYG200902003.htm
    [3]
    兰尧中, 刘进, 李现强, 等. 水合肼还原法制备超细银粉的研究. 贵金属, 2009, 26(4): 22 https://www.cnki.com.cn/Article/CJFDTOTAL-GJSZ200504006.htm

    Lan X Z, Liu J, Li X Q, et al. Preparation of silver powders by reduction method with hydrazine. Precious Met, 2009, 26(4): 22 https://www.cnki.com.cn/Article/CJFDTOTAL-GJSZ200504006.htm
    [4]
    帅英, 王献彪, 翟红侠. 甲醛还原制备超细球形银粉的工艺研究. 化工新型材料, 2011, 39(12): 80 https://www.cnki.com.cn/Article/CJFDTOTAL-HGXC201112026.htm

    Shuai Y, Wang X B, Zhai H X. Study on process of preparing ultrar-fine spherical silver powder by reduction method with formaldehyde. New Chem Mater, 2011, 39(12): 80 https://www.cnki.com.cn/Article/CJFDTOTAL-HGXC201112026.htm
    [5]
    李军义, 王东新, 孙本双, 等. 包覆分解法制备多层陶瓷电容器用超细Ni粉性能表征. 粉末冶金技术, 2013, 31(5): 360 DOI: 10.3969/j.issn.1001-3784.2013.05.008

    Li J Y, Wang D X, Sun B S, et al. Characterization of ultrafine nickel powder for MLCC fabricated by coated precursor thermal decomposition method. Powder Metall Technol, 2013, 31(5): 360 DOI: 10.3969/j.issn.1001-3784.2013.05.008
    [6]
    胡敏毅. 多层陶瓷电容器电极用超细铜粉的制备与表面改性研究, 长沙: 中南大学, 2008

    Hu M Y. Ultra Fine Copper Powder Fabrication and Surface Modification for MLCC Inner Electrode[Dissertation]. Changsha: Central South University, 2008
    [7]
    王岳俊, 周康根, 蒋志刚. 葡萄糖还原氢氧化铜制备球形氧化亚铜及其粒度控制研究. 无机化学学报, 2011, 27(12): 2405 https://www.cnki.com.cn/Article/CJFDTOTAL-WJHX201112016.htm

    Wang J Y, Zhou K G, Jiang Z G. Preparation and size control of spherical cuprous oxide particles by reducing cupric dioxide with glucose. Chin J Inorg Chem, 2011, 27(12): 2405 https://www.cnki.com.cn/Article/CJFDTOTAL-WJHX201112016.htm
    [8]
    刘志宏, 刘智勇, 李启厚, 等. 喷雾热分解法制备超细银粉及其形貌控制. 中国有色金属学报, 2007, 17(1): 149 https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ200701022.htm

    Liu Z H, Liu Z Y, Li Q H, et al. Morphology control of micro-sized spherical silver powder prepared by spray pyrolysis. Chin J Nonferrous Met, 2007, 17(1): 149 https://www.cnki.com.cn/Article/CJFDTOTAL-ZYXZ200701022.htm
    [9]
    施文锋. 高结晶度银粉的制备方法: 中国专利, CN102441675B. 2014-06-01

    Shi W F. Highly Crystalline Silver Powder and Making Method Thereof: China Patent, CN102441675B. 2014-06-01
    [10]
    黄凯, 郭学益, 张多默. 超细粉末湿法制备过程中粒子粒度和形貌控制的基础理论. 粉末冶金科学与工程, 2005, 10(6): 319 https://www.cnki.com.cn/Article/CJFDTOTAL-FMGC200506000.htm

    Huang K, Guo X Y, Zhang D M. Fundamental theories of particle size and morphology controlling for ultrafine powders in wet chemical precipitation process. Mater Sci Eng Powder Metall, 2005, 10(6): 319 https://www.cnki.com.cn/Article/CJFDTOTAL-FMGC200506000.htm
    [11]
    张传福, 蒋伟燕, 湛菁. 形貌控制合成棒状银粉前驱体. 贵金属, 2011, 32(3): 13 https://www.cnki.com.cn/Article/CJFDTOTAL-GJSZ201103002.htm

    Zhang C F, Jiang W Y, Zhan L. Preparation of rod precursor of silver powder. Precious Met, 2011, 32(3): 13 https://www.cnki.com.cn/Article/CJFDTOTAL-GJSZ201103002.htm
    [12]
    郑水林. 粉体表面改性. 北京: 中国建材工业出版社, 1995

    Zheng S L. Powder Surface Modification. Beijing: China Building Material Press, 1995
  • Related Articles

    [1]ZHANG Xiuling, CHEN Yuhong, QI Wubin, ZHANG Qiang, HAI Wanxiu. Densification and physical properties of SiC-diamond polycrystalline materials produced by pressureless sintering[J]. Powder Metallurgy Technology, 2024, 42(2): 165-169, 176. DOI: 10.19591/j.cnki.cn11-1974/tf.2021090009
    [2]WAN Lin, ZHANG Jifeng, SUN Lu, QIU Tianxu, SHEN Xiaoping. Effects of C and Cr contents on microstructure and physical properties of powder forged Fe–Cu–C–Cr alloys[J]. Powder Metallurgy Technology, 2023, 41(6): 508-515. DOI: 10.19591/j.cnki.cn11-1974/tf.2020090001
    [3]ZHANG Chen-zeng, CHEN Cun-guang, LI Pei, LU Tian-xing, YANG Fang, GUO Zhi-meng. Microstructure and properties of Cu‒Fe alloys prepared by powder metallurgy[J]. Powder Metallurgy Technology, 2022, 40(2): 139-144. DOI: 10.19591/j.cnki.cn11-1974/tf.2021040009
    [4]CHEN Jin, XIONG Ning, GE Qi-lu, WANG Tie-jun, CAI Jing, LIU Gui-Rong. Fabrication and properties of large size aluminum-based boron carbide composites by hot isostatic pressing[J]. Powder Metallurgy Technology, 2020, 38(2): 132-137. DOI: 10.19591/j.cnki.cn11-1974/tf.2020.02.008
    [5]ZHANG Bing-qing, WANG Qi, WANG Sui, WANG Hua-lei, JIANG Feng, SUN Jun. Study on the microstructure and properties of powder-forged gear materials[J]. Powder Metallurgy Technology, 2020, 38(2): 113-120. DOI: 10.19591/j.cnki.cn11-1974/tf.2020.02.005
    [6]ZHANG Ren, WANG Xu-lei, HE Xin-bo. Effect of Cr coating on microstructure and properties of graphite flake/Cu composites[J]. Powder Metallurgy Technology, 2019, 37(4): 248-254. DOI: 10.19591/j.cnki.cn11-1974/tf.2019.04.002
    [7]ZHOU Qiang, WEI Shi-chao, YANG Shu-zhong, LUO Li, CHANG De-min. Preparation of FeCuNiSnCo powder by mechanical alloying and the research on physical properties of its matrix material[J]. Powder Metallurgy Technology, 2019, 37(1): 30-35. DOI: 10.19591/j.cnki.cn11-1974/tf.2019.01.005
    [8]NI Feng, FU Li-hua, DENG Pan, WU Peng-fei. Effects of SiO2-B2O3-Al2O3 scaling powder on microstructures and properties of Cu-C-SnO2 porous materials sintered by powders[J]. Powder Metallurgy Technology, 2018, 36(5): 335-341. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.05.003
    [9]LIU Gui-min, DU Lin-fei, YAN Tao, ZHU Shuo, HUI Yang. Effect of rare earth Ce on the microstructure and properties of Cu-Al2O3 composites[J]. Powder Metallurgy Technology, 2018, 36(3): 196-200, 216. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.03.006
    [10]Thermophysical Properties of ZrCp/W Composites Prepared by Hot-pressing[J]. Powder Metallurgy Technology, 2002, 20(5): 263-266. DOI: 10.3321/j.issn:1001-3784.2002.05.001
  • Cited by

    Periodical cited type(17)

    1. 蔡锦文,冯可芹,王海波,刘艳芳,陈思潭. 表面修饰石墨烯制备工艺及其在金属材料中的应用研究. 材料导报. 2024(01): 158-163 .
    2. 陈施润,陈文革,钱颖,张辉. 稀土铈改性石墨烯/水性环氧树脂复合涂料涂装技术研究. 中国腐蚀与防护学报. 2024(01): 107-118 .
    3. 张可萌,柳培,王杰,侯博,刘振伟,高岩. Cu-(石墨烯/6063Al)复合材料的设计制备及组织性能研究. 粉末冶金工业. 2024(02): 75-80 .
    4. 冯俊俊,张会,李亚鹏,段瑾瑜,刘禹,蒲卓林. 石墨烯负载铜增强铜基块体复合材料的制备及其性能. 复合材料学报. 2023(01): 485-498 .
    5. 施琴,朱和军. 银包覆过渡族金属硒化物的制备及银基复合材料性能. 粉末冶金技术. 2023(06): 536-542 . 本站查看
    6. 陈华强,陶应啟,李晓静,吴云洪,王吉应,叶墨稼,余贤旺. 化学气相沉积法及机械混合法添加石墨烯对铜铬触头性能的影响. 功能材料. 2023(12): 12148-12153+12162 .
    7. 陈伟光,刘娟. 添加剂对传感器用PCB环氧树脂板真空蒸镀铜层参数优化及结构的影响. 材料保护. 2022(01): 159-164 .
    8. 李慧莹,王玄玉,孙淑宝,刘志龙,董文杰. 镀镍石墨烯制备及红外干扰性能. 含能材料. 2022(12): 1213-1218 .
    9. 文国富,梁艳娟,王秀飞,伊春强,尹彩流,蒙洁丽. 球磨参数对石墨烯增强铜基复合材料性能的影响. 润滑与密封. 2021(01): 103-110 .
    10. 马强,王健,韦琪龙,路承功,魏智强. 碳包覆CdS纳米颗粒的光学性能研究. 粉末冶金技术. 2021(01): 54-61 . 本站查看
    11. 梁燕,王献辉,李航宇,倪菁艺,金千贺. 石墨烯增强铜基复合材料的制备及研究现状. 稀有金属材料与工程. 2021(07): 2607-2619 .
    12. 施琴,朱和军. 银/石墨烯复合润滑添加剂对于润滑油摩擦性能的影响. 粉末冶金技术. 2020(04): 257-261+274 . 本站查看
    13. 赵敬,彭倚天. 石墨烯表面化学镀铜及铜/石墨烯复合材料的性能研究. 电镀与涂饰. 2020(21): 1481-1485 .
    14. 冯孟奇,贾淑果,李韶林,宋克兴,国秀花,张祥峰,林焕然. 铜/碳复合材料的研究进展. 材料热处理学报. 2020(12): 25-36 .
    15. 刘宇宁,彭冬冬,张辉,甘春雷. 烧结压力对石墨烯增强铜基复合材料组织性能的影响. 功能材料. 2019(01): 1183-1187+1191 .
    16. 郭申申,凤仪,赵浩,钱刚,张学斌. 石墨烯增强铜基复合材料的制备及其微观组织与性能研究. 金属功能材料. 2019(04): 16-22 .
    17. 巩正奇,王灿明,崔洪芝,张文娅. 石墨烯对激光熔覆镍基碳化钨涂层组织及性能影响. 粉末冶金技术. 2019(05): 323-331 . 本站查看

    Other cited types(8)

Catalog

    Article Metrics

    Article views (341) PDF downloads (32) Cited by(25)
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return