Citation: | CHEN Zexu, WU Dun, LIU Chunlin, CAO Zheng, CHENG Junfeng. Effect of surface treatment on powder injection molding performance of 316L stainless steel powders[J]. Powder Metallurgy Technology, 2023, 41(4): 289-295. DOI: 10.19591/j.cnki.cn11-1974/tf.2020110011 |
The 316L stainless steel powder injection molding feedstock was prepared by melt mixing with polyethylene glycol/epoxy resin (PEG-EP) as the powder surface modifier and polyformaldehyde resin (POM) as the binder system. The sintered 316L samples were obtained by nitric acid catalytic degreasing and sintering. The encapsulation effect of PEG-EP on 316L stainless steel powders and the influence of PEG-EP surface treatment on the properties of 316L stainless steel powder injection molding feedstock and the sintered specimens were studied by Fourier transform infrared spectroscope, scanning electron microscope, contact angle measuring instrument, rotary rheometer, universal material tester, metallographic microscope, carbon-sulfur analyzer, and microhardness meter. The results show that, PEG-EP are successfully coated on the surface of 316L steel powders, which improves the interface compatibility between 316L stainless steel powders and POM and enhances the feedstock fluidity, the mechanical properties of raw billets, and the mechanical properties and hardness of the sintered samples. When the PEG-EP mass fraction is 0.662% and the powder loading (volume fraction) is 63%, the tensile strength, fracture elongation, and bending strength of the 316L injection raw billets are 10.57 MPa, 8.38 %, and 21.24 N·(mm2)−1, respectively. The grain size, the maximum tensile strength, and the Vickers hardness of the sintered sample are 50.8 μm, 688 MPa, and 151 HV, respectively, leading to the best comprehensive performance.
[1] |
李流军, 李益民, 邓忠勇. 金属粉末注射成形生产设备及其发展趋势. 粉末冶金材料科学与工程, 2004(3): 212
Li L J, Li Y M, Deng Z Y. Metal powder injection molding production equipment and its development trend. Mater Sci Eng Powder Metall, 2004(3): 212
|
[2] |
Aslam M, Ahmad F, Yusoff P S, et al. Investigation of boron addition on densification and cytotoxicity of powder injection molded 316L stainless steel dental materials. Arabian J Sci Eng, 2016, 41(11): 4669 DOI: 10.1007/s13369-016-2224-1
|
[3] |
Abdullah A A, Norita H, Azlina H N, et al. Preparation of SS316L MIM feedstock with biopolymer as a binder. IOP Conf Ser Mater Sci Eng, 2018, 290(1): 012076
|
[4] |
贺毅强, 陈振华, 陈志钢. 金属粉末注射成形的原理与发展趋势. 材料科学与工程学报, 2013(2): 165
He Y Q, Chen Z H, Chen Z G. The principle and development trend of metal powder injection molding. J Mater Sci Eng, 2013(2): 165
|
[5] |
汪传生, 刘营, 胡纪全. 粘结剂含量对金属喂料流动性能的影响. 橡胶工业, 2017, 64(7): 431
Wang C S, Liu Y, Hu J Q. The influence of binder content on the flow properties of metal feeds. China Rubber Ind, 2017, 64(7): 431
|
[6] |
Hnatkova E, Hausnerova B, Hales A, et al. Processing of MIM feedstocks based on Inconel 718 powder and partially water-soluble binder varying in PEG molecular weight. Powder Technol, 2017, 322: 439 DOI: 10.1016/j.powtec.2017.09.029
|
[7] |
Hayat M D, Goswami A, Matthews S, et al. Modification of PEG/PMMA binder by PVP for titanium metal injection moulding. Powder Technol, 2017, 315: 243 DOI: 10.1016/j.powtec.2017.04.004
|
[8] |
Muhammad D H, Jadhav P P, Zhang H, et al. Improving titanium injection moulding feedstock based on PEG/PPC based binder system. Powder Technol, 2018, 330: 304 DOI: 10.1016/j.powtec.2018.02.043
|
[9] |
Liu W, Xie Z, Jia C. Surface modification of ceramic powders by titanate coupling agent for injection molding using partially water soluble binder system. J Eur Ceram Soc, 2012, 32(5): 1001 DOI: 10.1016/j.jeurceramsoc.2011.11.017
|
[10] |
刘超, 孔祥吉, 吴胜文, 等. 生物医用Ti6Al4V合金粉末注射成形工艺研究. 粉末冶金技术, 2018, 36(3): 217
Liu C, Kong X J, Wu S W, et al. Research on powder injection molding of Ti6Al4V alloys for biomedical application. Powder Metall Technol, 2018, 36(3): 217
|
[11] |
周晚珠, 朱杰, 李志, 等. FeCrBS预合金粉末对金属注射成形316L不锈钢烧结性能的影响. 粉末冶金技术, 2018, 36(4): 243
Zhou W Z, Zhu J, Li Z, et al. Effects of FeCrBSi pre-alloyed powder on sintering properties of 316L stainless steel by metal injection molding. Powder Metall Technol, 2018, 36(4): 243
|
[12] |
朱海洋. 金属粉末注射成型用新型聚醛基粘结剂的制备及应用[学位论文]. 合肥: 合肥工业大学, 2017
Zhu H Y. Preparation and Application of a New Polyaldehyde-Based Binder for Metal Powder Injection Molding [Dissertation]. Hefei: Hefei University of Technology, 2017
|
[13] |
豆亚坤. 316L不锈钢金属注射成形工艺及性能研究[学位论文]. 合肥: 合肥工业大学, 2016
Dou Y K. 316L Stainless Steel Metal Injection Molding Process and Performance Research [Dissertation]. Hefei: Hefei University of Technology, 2016
|
[14] |
Thavanayagam G, Pickering K L, Swan J E, et al. Analysis of rheological behaviour of titanium feedstocks formulated with a water-soluble binder system for powder injection moulding. Powder Technol, 2015, 269: 227 DOI: 10.1016/j.powtec.2014.09.020
|
[15] |
朱洪洲, 田春玲, 何丽红. 非离子型水性环氧树脂乳液的研制及性能研究. 化工新型材料, 2016(11): 226
Zhu H Z, Tian C L, He L H. Development and performance study of non-ionic waterborne epoxy resin emulsion. New Chem Mater, 2016(11): 226
|
[16] |
郑帼, 朱佳文, 周存. 自乳化非离子型环氧树脂的制备及性能研究. 中国塑料, 2017, 285(12): 28
Zheng W, Zhu J W, Zhou C. Preparation and performance study of self-emulsifying non-ionic epoxy resin. China Plast, 2017, 285(12): 28
|
[17] |
Liu Y, Zhou T, Chen Z, et al. Crystallization behavior and toughening mechanism of poly (ethylene oxide) in polyoxymethylene/poly (ethylene oxide) crystalline/crystalline blends. Polym Adv Technols, 2014, 25(7): 760 DOI: 10.1002/pat.3307
|
[18] |
Wen J X, Xie Z P, Cao W B. Novel fabrication of more homogeneous water-soluble binder system feedstock by surface modification of oleic acid. Ceram Int, 2016: 15530
|
[19] |
Li C L, Mei Q S, Li J Y, et al. Hall-Petch relations and strengthening of Al-ZnO composites in view of grain size relative to interparticle spacing. Scr Mater, 2018, 153: 27 DOI: 10.1016/j.scriptamat.2018.04.042
|
[20] |
高晓龙, 夏天东, 王晓军. 金属晶粒细化方法的研究现状. 金属功能材料, 2009, 16(6): 60
Gao X L, Xia T D, Wang X J. Present research status for metals refinement methods. Met Funct Mater, 2009, 16(6): 60
|
[21] |
刘倩, 唐靖林. 碳对镁铝合金晶粒细化影响的研究. 铸造技术, 2008, 29(11): 1498
Liu Q, Tang J L. Influence of carbon addition on grain refinement of magnesium-aluminum alloys. Foundry Technol, 2008, 29(11): 1498
|
1. |
李圆圆,吴莹,潘小强,刘廷伟. 放电等离子烧结制备碳化硼不锈钢复合材料. 粉末冶金技术. 2024(04): 381-387 .
![]() | |
2. |
陈梦熊,熊慧文,邹恒,欧阳德才,张雷,周科朝. 金属粉末增塑成形用聚甲醛基黏结剂发展现状及改性研究进展. 中南大学学报(自然科学版). 2024(08): 3032-3046 .
![]() | |
3. |
李晓芙,吴盾,曹峥,成骏峰,王东,刘春林. PEG功能化及其在粉末注射成型17-4PH不锈钢中的应用. 塑料科技. 2024(09): 45-50 .
![]() |