稀土掺杂Sr2MgSi2O7长余辉发光材料的研究进展

王岳; 武鑫江; 蔡永丰; 黄春草; 徐自林; 沈毅

doi:10.19591/j.cnki.cn11-1974/tf.2020.02.010

稀土掺杂Sr₂MgSi₂O₇长余辉发光材料的研究进展

doi: 10.19591/j.cnki.cn11-1974/tf.2020.02.010

华北理工大学材料科学与工程学院, 唐山 063210

基金项目:

国家自然科学基金资助项目 51772099

国家自然科学基金资助项目 51572069

华北理工大学大学生创新创业训练计划资助项目 X2018002

华北理工大学研究生创新项目 2018S06

详细信息

通讯作者:
沈毅, E-mail:shenyicyf@126.com

中图分类号: TB321
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出版历程
- 收稿日期: 2019-01-29
- 刊出日期: 2021-01-06

Research progress of rare earth doped Sr₂MgSi₂O₇ long afterglow luminescent materials

College of Material Science and Engineering, North China University of Science and Technology, Tangshan 063210, China

More Information

Corresponding author: SHEN Yi, E-mail:shenyicyf@126.com

摘要

摘要: 硅酸镁锶(Sr₂MgSi₂O₇)作为目前常用的一种长余辉发光材料基质, 性能稳定, 耐酸碱性能良好。本文介绍了长余辉发光材料的发光原理, 综述了近年来Sr₂MgSi₂O₇长余辉发光材料的主要制备方法以及稀土掺杂Sr₂MgSi₂O₇材料的研究进展, 并对该材料的发展做出了展望。制备Sr₂MgSi₂O₇长余辉发光材料的方法主要包括高温固相法, 溶胶-凝胶法, 化学沉淀法和燃烧合成法, 其中最常用的为高温固相法。通过掺杂稀土离子可以形成具有不同发光特性的长余辉发光材料。稀土掺杂Sr₂MgSi₂O₇材料作为一种储能、节能的长余辉发光材料, 展现出了广阔的发展和应用前景。
- 长余辉发光材料 /
- Sr₂MgSi₂O₇ /
- 稀土掺杂 /
- 研究进展
Abstract: As the commonly used long afterglow luminescent material matrix, Sr₂MgSi₂O₇ shows the stable performance and the superior acid and alkali resistance. The luminescence principle of long afterglow luminescence material was introduced in this paper, the preparation methods of Sr₂MgSi₂O₇ long afterglow luminescent materials were summarized, the rare earth doped Sr₂MgSi₂O₇ materials were reviewed, and the development of the materials were prospected. The preparation methods of Sr₂MgSi₂O₇ long afterglow luminescent materials include the high temperature solid state method, sol-gel method, chemical precipitation method, and chemical precipitation method, the most common method is the high temperature solid phase method. The long afterglow luminescent materials with different luminescence characteristics can be formed by doping rare earth ions. The rare earth doped Sr₂MgSi₂O₇ long afterglow luminescent materials for energy storage and energy conservation are present the broad development and application prospects.
- long afterglow luminescent materials /
- Sr₂MgSi₂O₇ /
- rare earth doping /
- research progress

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图 1 Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺的X射线衍射图谱^[39]

Figure 1. XRD patterns of Sr₂MgSi₂O₇: Eu²⁺, Dy^3+[39]

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图 2 不同烧结温度下Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺样品的激发光谱（a）和发射光谱（b）^[30]

Figure 2. Excitation (a) and emission spectra (b) of Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺ at different sintering temperatures^[30]

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图 3 Eu²⁺, Er³⁺共掺杂Sr₂MgSi₂O₇样品衰减曲线^[20]：（a）初始600 s；（b）最后600 s

Figure 3. Decay curves of the Eu²⁺, Er³⁺ co-doped Sr₂MgSi₂O₇ samples^[20]: (a) the initial 600 s; (b) the last 600 s

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图 4 Eu²⁺掺杂和Eu²⁺, La³⁺共掺杂Sr₂MgSi₂O₇热释光曲线^[42]

Figure 4. TL curves of Eu²⁺ doped and Eu²⁺, La³⁺ co-doped Sr₂MgSi₂O₇^[42]

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图 5 Eu²⁺, Dy³⁺, Nd³⁺共掺杂Sr₂MgSi₂O₇样品衰减曲线^[17]

Figure 5. Decay curves of the Eu²⁺, Dy³⁺, Nd³⁺ co-doped Sr₂MgSi₂O₇ samples^[17]

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图 6 Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺（a）和Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺, Nd³⁺（b）显微形貌图^[44]

Figure 6. SEM images of Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺ (a) and Sr₂MgSi₂O₇: Eu²⁺, Dy³⁺, Nd³⁺ (b) ^[44]

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