钛及钛合金粉末制备与成形工艺研究进展

杨芳; 李延丽; 申承秀; 王春官; 陈存广; 何新波; 郭志猛

doi:10.19591/j.cnki.cn11-1974/tf.2021030037

钛及钛合金粉末制备与成形工艺研究进展

doi: 10.19591/j.cnki.cn11-1974/tf.2021030037

杨芳^{1, 2, ,},
李延丽¹,
申承秀³,
王春官³,
陈存广^{1, 2},
何新波^{1, 2},
郭志猛^{1, 2}

1.
北京科技大学新材料技术研究院, 北京 100083
2.
南方海洋科学与工程广东省实验室(珠海), 珠海 519082
3.
海安县通用粉末冶金厂, 南通 226699

基金项目: 国家自然科学基金资助项目（52004027）；南方海洋科学与工程广东省实验室（珠海）创新团队建设项目（311021013）

详细信息

通讯作者:
E-mail: yangfang@ustb.edu.cn

中图分类号: TF823
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出版历程
- 收稿日期: 2021-04-18
- 刊出日期: 2023-08-29

Research progress on preparation and forming of titanium andtitanium alloy powders

YANG Fang^{1, 2
, ,},
LI Yanli¹,
SHEN Chengxiu³,
WANG Chunguan³,
CHEN Cunguang^{1, 2},
HE Xinbo^{1, 2},
GUO Zhimeng^{1, 2}

1.
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
2.
Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Zhuhai 519082, China
3.
Haian County Tongyong Powder Metallurgy Factory, Nantong 226699, China

More Information

Corresponding author: E-mail: yangfang@ustb.edu.cn

摘要

摘要: 钛及钛合金因具有密度低、强度高、耐腐蚀、生物相容性好等特点被广泛应用于军事、航空、医疗等领域。传统铸锻钛合金生产工艺复杂，成本高，严重限制了钛合金的应用，粉末冶金技术制备钛合金降低了生产成本，有利于钛合金的推广应用。本文从钛及钛合金粉末的制备与成形工艺方面介绍了粉末冶金钛及钛合金的研究现状，并阐述了其发展趋势。
- 粉末冶金 /
- 钛及钛合金 /
- 粉末制备 /
- 成形工艺 /
- 研究进展
Abstract: Titanium and titanium alloys are widely used in military, aviation, and medical fields due to the low density, high strength, corrosion resistance, and good biocompatibility. The traditional production method of casting-forging titanium alloys is complicated and costly, which seriously limits the application of titanium alloys. Powder metallurgy technology can reduce the production cost of titanium alloys, which is expected to popularize the application of titanium alloys. The research status of titanium and titanium alloys by powder metallurgy was introduced in this paper from the aspects of powder preparation and forming process, and the development trend was described.
- powder metallurgy /
- titanium and titanium alloys /
- powder preparation /
- forming technology /
- research progress

HTML全文

图 1 不同尺寸氢化脱氢钛粉显微形貌^[6]

Figure 1. Microstructures of HDH titanium powders with different particle size^[6]

下载: 全尺寸图片幻灯片

图 2 CaCl₂、TiO₂质量比为1:4混合后制备的钛粉显微形貌^[24]

Figure 2. Microstructure of the titanium powders prepared by mixing CaCl₂ and TiO₂ with mass ratio of 1:4^[24]

下载: 全尺寸图片幻灯片

图 3 雾化法制备的球形钛粉显微形貌^[29]

Figure 3. Microstructure of the spherical titanium powders prepared by atomization method^[29]

下载: 全尺寸图片幻灯片

图 4 射频等离子体一体化球化制粉原理图^[33]

Figure 4. Schematic diagram of the radiofrequency plasma integration spheroidizing powders^[33]

下载: 全尺寸图片幻灯片

图 5 3D打印钛合金轮毂

Figure 5. 3D-printed titanium wheel hubs

下载: 全尺寸图片幻灯片

图 6 粉末冶金TC16棒材的宏观形貌^[40]

Figure 6. Macroscopic appearance of the powder metallurgy TC16 bars^[40]

下载: 全尺寸图片幻灯片

图 7 不同规格形状的粉末冶金钛合金烧结坯^[17]

Figure 7. Sintered billets of the powder metallurgy titanium alloys with different specifications and shapes^[17]

下载: 全尺寸图片幻灯片

表 1 钛粉制备工艺

Table 1. Preparation technology of the titanium powders

制粉方法	原料	粉末形貌	工艺及粉末特点
氢化脱氢法	电解钛或海绵钛	不规则形状	成本低，工艺简单，粉末粒度范围宽，O、N含量高
还原法	四氯化钛或二氧化钛	海绵形	O、N等杂质含量低，纯度高，流动性好，需要后续分离过程
雾化法	钛丝	球形	杂质含量低，球形度好，粒度大小均匀，粒度较粗
射频等离子体球化法	氢化钛颗粒	球形	纯度高，表面形貌好，内部空隙少，流动性好，生产技术较难

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