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Volume 36 Issue 5
Aug.  2021
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WANG Yan, GUO Chun, KONG De-cheng, ZHAO Zhen-jiang, WANG Li, DONG Chao-fang. Microstructures and corrosion failure analysis of zinc anode[J]. Powder Metallurgy Technology, 2018, 36(5): 348-354. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.05.005
Citation: WANG Yan, GUO Chun, KONG De-cheng, ZHAO Zhen-jiang, WANG Li, DONG Chao-fang. Microstructures and corrosion failure analysis of zinc anode[J]. Powder Metallurgy Technology, 2018, 36(5): 348-354. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.05.005
shu

Microstructures and corrosion failure analysis of zinc anode

  • 1.

    No. 704 Research Institute, China Shipbuilding Industry Corporation, Shanghai 200031, China

  • 2.

    Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

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  • Corresponding author:

    WANG Yan, E-mail: penny0115@163.com

  • Received Date: February 21, 2018
    Graphical Abstract
    • Abstract
  • A corrosion product layer in the thickness of about 1 mm was formed on the failed zinc anode surface, and the non-conducting corrosion product was strongly bonded to the substrate, leading to the failure of anode protection. The corrosion products of zinc anode surface showed the obvious layered structure, which was mostly in flake-like and partly in spherical. The sheet products were mainly Zn12(SO4)3Cl3(OH)5·5H2O and Zn4SO4(OH)6·5H2O, and the spherical products were mainly Zn5(OH)8Cl2·H2O; the contents of Pb, Cu, and Fe by mass were slightly exceeded standard in the failed zinc block, resulting in the decrease of zinc protection efficiency. If the sacrificial anode was disturbed by stray current, its surface would be deactivated by rapid polarization; when the sacrificial anode was polarized by the constant current of 0.1 mA·cm-2 for 10 h, the zinc surface would be in polarization passivation state soon, losing the sacrifice protection.
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    • References (10)
  • [1]
    Syrett B C, Macdonald D D, Wing S S. Corrosion of copper-nickel alloys in sea water polluted with sulfide and sulfide oxidation products. Corros, 1979, 35(9): 409 DOI: 10.5006/0010-9312-35.9.409
    [2]
    Metikoš-Huković M, Škugor I, Grubač Z, et al. Complexities of corrosion behaviour of copper-nickel alloys under liquid impingement conditions in saline water. Electrochim Acta, 2010, 55(9): 3123 DOI: 10.1016/j.electacta.2010.01.066
    [3]
    Ismail K M, Fathi A M, Badawy W A. Electrochemical behavior of copper-nickel alloys in acidic chloride solutions. Corros Sci, 2006, 48(8): 1912 DOI: 10.1016/j.corsci.2005.07.004
    [4]
    钱晖, 冯斌, 王加明. 凝汽器铜管硫酸亚铁一次成膜的应用. 湖南电力, 2000, 20(1): 29 https://www.cnki.com.cn/Article/CJFDTOTAL-HNDL200001011.htm

    Qian H, Feng B, Wang J M. Application of primary ferrous sulfate film formation in copper tube of condenser. Hunan Electr Power, 2000, 20(1): 29 https://www.cnki.com.cn/Article/CJFDTOTAL-HNDL200001011.htm
    [5]
    Wagner P, Little B, Hart K, et al. Environmental fate of sacrificial zinc anodes and influence of a biofilm. Int Biodeterior Biodegrad, 1996, 37(3-4): 151 DOI: 10.1016/S0964-8305(96)00013-3
    [6]
    Dickinson W H, Caccavo Jr F, Lewandowski Z. The ennoblement of stainless steel by manganic oxide biofouling. Corros Sci, 1996, 38(8): 1407 DOI: 10.1016/0010-938X(96)00031-5
    [7]
    王凤平, 曹丽, 刘照斌, 等. Zn-Al-Cd合金对20#钢牺牲阳极保护行为. 腐蚀科学与防护技术, 2015, 27(5): 431 https://www.cnki.com.cn/Article/CJFDTOTAL-FSFJ201505006.htm

    Wang F P, Cao L, Liu Z B, et al. Protective performance of Zn-Al-Cd alloy sacrificial anode for 20#steel. Corros Sci Prot Technol, 2015, 27(5): 431 https://www.cnki.com.cn/Article/CJFDTOTAL-FSFJ201505006.htm
    [8]
    李异, 李永广. 在役海底管线牺牲阳极失效分析. 中国腐蚀与防护学报, 2002, 22(1): 60 DOI: 10.3969/j.issn.1005-4537.2002.01.013

    Li Y, Li Y G. The analysis for failure Al sacrificial anode used in sea bed pipelines. J Chin Soc Corros Prot, 2002, 22(1): 60 DOI: 10.3969/j.issn.1005-4537.2002.01.013
    [9]
    Sziráki L, Cziráki A, Geröcs I, et al. A kinetic model of the spontaneous passivation and corrosion of zinc in near neutral Na2SO4 solutions. Electrochim Acta, 1998, 43(1-2): 175 DOI: 10.1016/S0013-4686(97)00223-5
    [10]
    方景, 陈刚, 司朝霞. 热浸镀锌对铁基粉末冶金零件耐腐蚀性的影响. 粉末冶金技术, 2008, 26(6): 452 https://www.cnki.com.cn/Article/CJFDTOTAL-FMYJ200806013.htm

    Fang J, Chen G, Si Z X. Effects of hot galvanizing on the corrosion-resistance of iron-based powder metallurgy parts. Powder Metall Technol, 2008, 26(6): 452 https://www.cnki.com.cn/Article/CJFDTOTAL-FMYJ200806013.htm
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