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Volume 43 Issue 1
Jan.  2025
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ZHOU Hongdeng, ZHANG Yuling, XIA Chunlin, TIAN Qingchao. Oxidation behavior of molybdenum alloy coatings at 1200 ℃[J]. Powder Metallurgy Technology, 2025, 43(1): 123-133. DOI: 10.19591/j.cnki.cn11-1974/tf.2023060008
Citation: ZHOU Hongdeng, ZHANG Yuling, XIA Chunlin, TIAN Qingchao. Oxidation behavior of molybdenum alloy coatings at 1200 ℃[J]. Powder Metallurgy Technology, 2025, 43(1): 123-133. DOI: 10.19591/j.cnki.cn11-1974/tf.2023060008
shu

Oxidation behavior of molybdenum alloy coatings at 1200 ℃

  • 1.

    State Key Laboratory of Advanced Special Steel, Shanghai University, Shanghai 200444, China

  • 2.

    Avic Guizhou Anda Aviation Forging Co., Ltd., Anshun 561005, China

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  • Corresponding author:

    TIAN Qingchao, E-mail: tctian@shu.edu.cn

  • Received Date: October 18, 2023
  • Accepted Date: October 18, 2023
  • Available Online: October 20, 2023
    Graphical Abstract
    • Abstract

  • Three different coatings A, B and C were prepared on TZC molybdenum alloy surface by coating method. The A coating contains borosilicate glass, the B coating dopes MoSi2 powder with A mass fraction of 15% on the basis of the A coating, and the C coating adds a small amount of Al powder on the basis of the B coating. The oxidation behavior of the coatings at 1200 ℃ was studied by heating furnace, X-ray diffraction analyzer and scanning electron microscope. The results show that the C coating has a good protection performance within 1 h of high temperature oxidation, and the oxidation resistance of the C coating after 2 hours is 69% higher than that without coating protection. After high temperature oxidation, the cross-section morphology of A coating and B coating is dominated by the loose structure of MoO3 and TiO2 alternately distributed. The addition of aluminum powder changes the phase composition of the oxide film, and the C coating forms a three-layer structure of the outer aluminosilicate, the middle cerium titanium oxide, the inner TiO2 and molybdenum silicon compound, which makes it have excellent oxidation resistance.

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    • References (28)
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