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Volume 42 Issue 1
Feb.  2024
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LONG Hangfei, YE Jinwen, CAO Zhinan. Effect of (Cr,La)2(C,N) addition on the structure and properties of Ti(C,N)-based cermets[J]. Powder Metallurgy Technology, 2024, 42(1): 45-52. doi: 10.19591/j.cnki.cn11-1974/tf.2021100002
Citation: LONG Hangfei, YE Jinwen, CAO Zhinan. Effect of (Cr,La)2(C,N) addition on the structure and properties of Ti(C,N)-based cermets[J]. Powder Metallurgy Technology, 2024, 42(1): 45-52. doi: 10.19591/j.cnki.cn11-1974/tf.2021100002

Effect of (Cr,La)2(C,N) addition on the structure and properties of Ti(C,N)-based cermets

doi: 10.19591/j.cnki.cn11-1974/tf.2021100002
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  • Corresponding author: E-mail: yjw550@163.com
  • Received Date: 2021-12-06
  • Publish Date: 2024-02-28
  • (Cr,La)2(C,N) powders were prepared by the high temperature carbon tube furnace in an open system, using as the additive to prepare the Ti(C,N)-based cermets. The effects of (Cr,La)2(C,N) on the microstructure and mechanical properties of the Ti(C,N)-based cermets were studied by X-ray diffraction (XRD), scanning electron microscope (SEM), universal mechanical testing machine, and Vickers hardness tester. The results show that the addition of (Cr,La)2(C,N) can effectively refine the hard phase grains of the Ti(C,N)-based cermets. The Cr and La elements are mainly dissolved in the binder phase, and the La element promotes the dissolution and precipitation process of the hard phase. Furthermore, the bending strength, hardness, and fracture toughness of the cermets are significantly improved. When the mass fraction of (Cr,La)2(C,N) is 5.0%, the comprehensive mechanical properties of the Ti(C,N)-based cermets are the best, the bending strength is 2002 MPa, the Vickers hardness is 1643 MPa, and the fracture toughness is 11.22 MPa·m1/2.
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  • [1]
    吴悦梅, 周黎明, 熊计, 等. WC和Mo2C的添加对Ti(C,N)基金属陶瓷高温显微硬度的影响. 机械工程材料, 2017, 41(7): 24 doi: 10.11973/jxgccl201707005

    Wu Y M, Zhou L M, Xiong J, et al. Effect of WC and Mo2C addition on microhardness of Ti(C,N)-based cermets at high temperature. Mater Mech Eng, 2017, 41(7): 24 doi: 10.11973/jxgccl201707005
    [2]
    刘嘉威, 古思勇, 陈莹, 等. 水解沉淀–碳热还原氮化法制备碳氮化钛粉末. 粉末冶金技术, 2021, 39(1): 89

    Liu J W, Gu S Y, Chen Y, et al. Synthesis of Ti(C,N) powders by hydrolysis precipitation‒carbothemal reduction and nitridation method. Power Metall Tchnol, 2021, 39(1): 89
    [3]
    Wang J, Liu Y, Ye J W. Evolution of phase microstructure and properties of mulit-core cermets based on (Ti,W,Ta) CN and TiCN powders in sintering process. Rare Met Mater Eng, 2018, 47(5): 1385 doi: 10.1016/S1875-5372(18)30139-5
    [4]
    Yan H, Deng Y, Jiang S, et al. Preparation of Ti(C,N)-based cermets powders with double-core ring structure. IOP Conf Ser Mater Sci Eng, 2019, 569: 022014 doi: 10.1088/1757-899X/569/2/022014
    [5]
    李傲奇, 许里伟, 吝楠, 等. WC与Mo2C的添加对Ti(C,N)基金属陶瓷显微组织和耐腐蚀性能的影响. 精密成形工程, 2021, 13(2): 13

    Li A Q, Xu L W, Lin N, et al. Effect of WC and Mo2C additions on microstructure and corrosion resistance of Ti(C,N)-based cermet. J Netsh Form Eng, 2021, 13(2): 13
    [6]
    陈敏, 肖玄, 张雪峰. TaC含量对TiCN基金属陶瓷组织与性能的影响. 粉末冶金材料科学与工程, 2016, 21(2): 270 doi: 10.3969/j.issn.1673-0224.2016.02.013

    Chen M, Xiao X, Zhang X F. Effect of TaC content on microstructure and properties of TiCN-based cermets. Mater Sci Eng Powder Metall, 2016, 21(2): 270 doi: 10.3969/j.issn.1673-0224.2016.02.013
    [7]
    赵永乐, 赵能伟, 刘林艳, 等. Cr3C2对Ti(C, N)基金属陶瓷性能的影响. 硬质合金, 2008, 25(1): 1

    Zhao Y L, Zhao N W, Liu L Y, et al. Effect of the content of Cr3C2 on Ti(C, N) based cermets. Cement Carb, 2008, 25(1): 1
    [8]
    刘宁, 胡镇华, 崔昆, 等. 钇对金属陶瓷力学性能和组织的影响. 中国稀土学报, 1997, 15(1): 80 doi: 10.3321/j.issn:1000-4343.1997.01.018

    Liu N, Hu Z H, Cui K, et al. Effect of Y on the mechanical properties and microstructure of cermets. J Chin Soc Rare Earths, 1997, 15(1): 80 doi: 10.3321/j.issn:1000-4343.1997.01.018
    [9]
    Wu X B, Zhou S Z, Wu F J, et al. Strengthening of solid solution (Ti,La)(C,N)-based cermets by LaB6 addition. Int J Refract Met Hard Mater, 2021, 95: 105443 doi: 10.1016/j.ijrmhm.2020.105443
    [10]
    董洪峰, 郭从盛, 张锋刚. 添加氧化镧WC–11Co–2.1TaC硬质合金的组织及性能. 陕西理工学院学报(自然科学版), 2016, 32(5): 1

    Dong H F, Guo C S, Zhang F G. Microstructure and properties of WC–11Co–2.1TaC cemented carbides by adding La2O3. J Shaanxi Univ Technol Nat Sci, 2016, 32(5): 1
    [11]
    姜佳庚, 周书助, 谭璟颢, 等. (Ti, La)(C, N)基金属陶瓷复合材料制备及性能研究. 硬质合金, 2019, 36(2): 109

    Jiang J G, Zhou S Z, Tan J H, et al. Preparation and properties of (Ti,La)(C,N)-based cermet composites. Cement Carb, 2019, 36(2): 109
    [12]
    Zhao L B, Lin N, He Y H. Improvement in microstructure and properties of Ti(C,N)-based cermets with Ruthenium additions. Ceram Int, 2018, 44(14): 17553 doi: 10.1016/j.ceramint.2018.06.156
    [13]
    Rolander U, Weinl G, Zwinkels M. Effect of Ta on structure and mechanical properties of (Ti,Ta,W)(C,N)–Co cermets. Int J Refract Met Hard Mater, 2001, 19: 325 doi: 10.1016/S0263-4368(01)00042-7
    [14]
    Park S, Kang S. Toughened ultra-fine (Ti,W)(CN)–Ni cermets. Scr Mater, 2005, 52(2): 129 doi: 10.1016/j.scriptamat.2004.09.017
    [15]
    汪金文, 刘宁, 徐伟, 等. Cr3C2对纳米Ti(C,N)基金属陶瓷组织和性能的影响. 热处理, 2011, 26(2): 14

    Wang J W, Liu N, Xu W, et al. Effect of Cr3C2 on microstructure and properties of nanoscale Ti(C,N)-based cermets. Heat Treat, 2011, 26(2): 14
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