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Oxidation behavior of molybdenum alloy coatings at 1200℃[J]. Powder Metallurgy Technology.
Citation: Oxidation behavior of molybdenum alloy coatings at 1200℃[J]. Powder Metallurgy Technology.

Oxidation behavior of molybdenum alloy coatings at 1200℃

  • Three coatings of which containing borosilicate glass and being doped with MoSi2 and aluminum powder were prepared on the surface of TZC molybdenum alloy using a coating method, and the oxidation behavior of the coatings at 1200 ℃ was studied using heating furnace, X-ray diffraction analyzer, and scanning electron microscope. The results show that the aluminum powder modified coating has good protective performance within 1 hour, and the oxidation resistance after 2 hours is 69% higher than that without coating protection. Research has found that the cross-section of borosilicate glass and MoSi2 doped coating is mainly composed of a loose structure with alternating distribution of MoO3 and TiO2 after oxidation, while the addition of Al powder changes the phase composition of the oxide film, forming a three-layer structure of outer aluminum silicate, middle cerium titanium oxide, and inner TiO2 and molybdenum silicon compound, making it have excellent antioxidant effect.
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    通讯作者: 陈斌, bchen63@163.com
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      沈阳化工大学材料科学与工程学院 沈阳 110142

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