AdvancedSearch
YANG Hai-yan, ZHANG Wang-nian, DENG Ning, XU Huan, LIU Yong-hui, SU Rui. Influence of NiO doping on the sintered properties of magnesite[J]. Powder Metallurgy Technology, 2019, 37(4): 279-282, 287. DOI: 10.19591/j.cnki.cn11-1974/tf.2019.04.007
Citation: YANG Hai-yan, ZHANG Wang-nian, DENG Ning, XU Huan, LIU Yong-hui, SU Rui. Influence of NiO doping on the sintered properties of magnesite[J]. Powder Metallurgy Technology, 2019, 37(4): 279-282, 287. DOI: 10.19591/j.cnki.cn11-1974/tf.2019.04.007

Influence of NiO doping on the sintered properties of magnesite

More Information
  • Corresponding author:

    ZHANG Wang-nian, E-mail: zwn2003@126.com

  • Received Date: September 24, 2018
  • The magnesite doped by NiO powders in different mass fractions was prepared by high-temperature calcination using natural magnesite as the raw materials in this study. The effects of NiO doping on the sintered properties, phase composition, and microstructures of magnesite were characterized by apparent porosity tester, X-ray diffractometer, and scanning electron microscope. The results show that, the NiO doping can improve the compactness of magnesite and promote the growth of MgO grain. Without the NiO doping, the line rate, bulk density, and apparent porosity of the magnesite after sintering at 1600℃ are 8.72%, 2.96 g·cm-3, and 19.2%, respectively, and the particle size of MgO is 1.36 μm. The line rate, bulk density, and apparent porosity of the magnesite doped by NiO powders in the mass fraction of 0.75% after sintering at 1600℃ are 18.06%, 3.29 g·cm-3, and 11.5%, respectively, and the particle size of MgO reaches to 3.81 μm. The sintered magnesite doped by NiO powders at 1600℃ can lead to the complete solid solution bewteen MgO and NiO, cause the lattice distortion of MgO, reduce the activation energy of grain growth, and consequentially promote the sintering compactness of the magnesite. But, the over-dose NiO doping may result in the partial solid solution bewteen MgO and NiO within a short time, impede the direct contact of sintered phases, obstruct the mass transfer process, and consequentially lower the sintering compactness of the magnesite.
  • [1]
    袁锐. 用菱镁矿粉矿制备高纯镁砂的研究. 中国非金属矿工业导刊, 2003, 36(5): 24 DOI: 10.3969/j.issn.1007-9386.2003.05.007

    Yuan Y. High-purity dead-burned magnesia made from magnesite powder. China Non-met Min Ind Her, 2003, 36(5): 24 DOI: 10.3969/j.issn.1007-9386.2003.05.007
    [2]
    Li Z, Zhang S, Lee W E. Improving the hydration resistance of lime-based refractory materials. Int Mater Rev, 2008, 53(1): 1 DOI: 10.1179/174328007X212508
    [3]
    Chen M, Lu C Y, Yu J K. Improvement in performance of MgO-CaO refractories by addition of nano-sized ZrO2. J Eur Ceram Soc, 2007, 27(16): 4633 http://www.sciencedirect.com/science/article/pii/S0955221907003317
    [4]
    Yeprem H A. Effect of iron oxide addition on the hydration resistance and bulk density of doloma. J Eur Ceram Soc, 2007, 27(2-3): 1651 DOI: 10.1016/j.jeurceramsoc.2006.05.010
    [5]
    李环, 苏莉, 于景坤. 高密度烧结镁砂的研究. 东北大学学报(自然科学版), 2007, 28(3): 381 DOI: 10.3321/j.issn:1005-3026.2007.03.020

    Li H, Su L, Yu J K. Investigation on process flow of high-density magnesia. J Northeastern Univ Nat Sic, 2007, 28(3): 381 DOI: 10.3321/j.issn:1005-3026.2007.03.020
    [6]
    占丹, 黄琳, 肖作安, 等. 流变相-前驱物法制备纳米氧化镁粉体. 化学试剂, 2007, 29(3): 141 DOI: 10.3969/j.issn.0258-3283.2007.03.005

    Zhan D, Huang L, Xiao Z A, et al. Preparation of nanometer magnesium oxide powder by rheology phase-precursor method. Chem Reag, 2007, 29(3): 141 DOI: 10.3969/j.issn.0258-3283.2007.03.005
    [7]
    朱亚先, 曾人杰, 刘新锦, 等. MgO纳米粉制备及表征. 厦门大学学报(自然科学版), 2001, 40(6): 1256 DOI: 10.3321/j.issn:0438-0479.2001.06.015

    Zhu Y X, Zhen R J, Liu X J, et al. Preparation and characterization of MgO nanopowder. J Xiamen Univ Nat Sic, 2001, 40(6): 1256 DOI: 10.3321/j.issn:0438-0479.2001.06.015
    [8]
    桂明玺. 添加氧化镍对提高镁砂的抗水化性能所起的效果. 国外耐火材料, 2005, 30(3): 35 https://www.cnki.com.cn/Article/CJFDTOTAL-GWLH200503010.htm

    Gui M X. Effect of NiO on slaking resistance of magnesia clinker. Foreign Refract, 2005, 30(3): 35 https://www.cnki.com.cn/Article/CJFDTOTAL-GWLH200503010.htm
    [9]
    郑子樵, 李红英. 稀土功能材料. 北京: 化学工业出版社, 2003

    Zheng Z Q, Li H Y. Rare Earth Functional Materials. Beijing: Chemical Industry Press, 2003
    [10]
    刘磊, 王周福, 何俊鹏, 等. Y2O3和CeO2对镁砂烧结性能及显微结构的影响. 耐火材料, 2012, 46(5): 340 https://www.cnki.com.cn/Article/CJFDTOTAL-LOCL201205007.htm

    Liu L, Wang Z F, He J P, et al. Effects of Y2O3 and CeO2 on sintering and microstructure of magnesite. Refractories, 2012, 46(5): 340 https://www.cnki.com.cn/Article/CJFDTOTAL-LOCL201205007.htm
    [11]
    王周福, 徐自伟, 张保国, 等. 混合稀土氧化物对镁质耐火材料结构与性能的影响. 稀有金属材料与工程, 2007, 36(增刊2): 373 https://www.cnki.com.cn/Article/CJFDTOTAL-COSE2007S2109.htm

    Wang Z F, Xu Z W, Zhang B G, et al. Effect of mixture of rare earth oxides on microstructure and properties of magnesia refractory. Rare Met Mater Eng, 2007, 36(Suppl 2): 373 https://www.cnki.com.cn/Article/CJFDTOTAL-COSE2007S2109.htm
    [12]
    Chaudhuri M, Banerjee G, Kumar A, e al. Secondary phases in natural magnesite sintered with addition of titania, ilmenite and zirconia. J Mater Sci, 1999, 34(23): 5821 DOI: 10.1023/A:1004718503991
    [13]
    Lee Y B, Park H C, Oh K D, et al. Sintering and microstructure development in the system MgO–TiO2. J Mater Sci, 1998, 33(17): 4321 DOI: 10.1023/A%3A1004443728590
    [14]
    Martinac V, Labor M, Petric N. Effect of TiO2, SiO2 and Al2O3 on properties of sintered magnesium oxide from sea water. Mater Chem Phys, 1996, 46(1): 23 http://www.sciencedirect.com/science/article/pii/0254058496801258
    [15]
    张汪年, 王利, 邓宁, 等. CoO对菱镁矿制备镁砂性能的影响. 粉末冶金技术, 2018, 36(4): 292 DOI: 10.19591/j.cnki.cn11-1974/tf.2018.04.009

    Zhang W N, Wang L, Deng N, et al. Effect of CoO addition on the preparation of magnesia by magnesite. Powder Metall Technol, 2018, 36(4): 292 DOI: 10.19591/j.cnki.cn11-1974/tf.2018.04.009
  • Related Articles

    [1]YU Zhanxiang, HE Fang, XIE Gaoshang. Effect of Cr on the properties and microstructure of nickel aluminum metal bond[J]. Powder Metallurgy Technology, 2024, 42(4): 374-380, 387. DOI: 10.19591/j.cnki.cn11-1974/tf.2022110001
    [2]TANG Yanyuan, YANG Qiumin, XU Guozuan, WANG Hongyun, ZHONG Zhiqiang. Effect of trace Y2O3 on microstructure and properties of WC−6Co cemented carbides with inhomogeneous structure[J]. Powder Metallurgy Technology, 2024, 42(2): 184-191. DOI: 10.19591/j.cnki.cn11-1974/tf.2021120008
    [3]Research Progress on the Powders Preparation, Densification sintering, Microstructure and Properties of Tungsten Diboride (WB2)[J]. Powder Metallurgy Technology. DOI: 10.19591/j.cnki.cn11-1974/tf.2023120001
    [4]The Effect of Sintering Temperature on the Microstructure and Mechanical Properties of β-Sialon Ceramics with Y2O3-Al2O3-ZrO2 Composite Sintering Additive[J]. Powder Metallurgy Technology. DOI: 10.19591/j.cnki.cn11-1974/tf.2024110008
    [5]YANG Fang, GAO Yang, DU Peng, CHEN Leiming, CHENG Junwei. Microstructure and mechanical properties of WC-based cemented carbides with different binder phases[J]. Powder Metallurgy Technology, 2023, 41(2): 187-192. DOI: 10.19591/j.cnki.cn11-1974/tf.2020060003
    [6]LIU Zeng-lin, HAN Wei, WANG Yan-kang, WANG Tao, LÜ Wei-long. Microstructure and mechanical properties of diffusion alloyed steel composites reinforced by ceramic particles[J]. Powder Metallurgy Technology, 2022, 40(6): 527-534. DOI: 10.19591/j.cnki.cn11-1974/tf.2021120007
    [7]YU Chen-xu. Fabrication, microstructure, and properties of W–Re/graphite composites[J]. Powder Metallurgy Technology, 2021, 39(5): 417-422. DOI: 10.19591/j.cnki.cn11-1974/tf.2021030024
    [8]REN Wei. Property characterization of Mn-Si powder porous alloy for semiconductors prepared by solid phase sintering[J]. Powder Metallurgy Technology, 2019, 37(6): 456-460. DOI: 10.19591/j.cnki.cn11-1974/tf.2019.06.009
    [9]ZHANG Wang-nian, DENG Ning, PENG Li-li. Effect of CaCO3 addition on the properties of CaZrO3[J]. Powder Metallurgy Technology, 2019, 37(1): 46-49, 56. DOI: 10.19591/j.cnki.cn11-1974/tf.2019.01.008
    [10]WANG Da-peng, MU Yun-chao, CHENG Xiao-zhe, ZHANG Wu-qi. Effects of raw material ratio on the properties of molybdenum carbide prepared by spark plasma sintering method[J]. Powder Metallurgy Technology, 2018, 36(1): 31-35. DOI: 10.19591/j.cnki.cn11-1974/tf.2018.01.006

Catalog

    Article Metrics

    Article views (251) PDF downloads (11) Cited by()
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return